Improvements in or relating to encapsulated perfume compositions

ABSTRACT

Disclosed are perfume compositions containing perfume ingredients selected on the basis that they are able to be stably incorporated into core-shell microcapsules. Perfume selection rules are based on a molecular descriptor of the electron density distribution within a perfume ingredient—RECON VOLTAE. Perfume ingredients having known RECON_VOLTAE values larger than about 1200 Bohr 3 , more particularly larger than 1540 Bohr 3 , and more particularly still larger than about 1750 Bohr 3  are particularly suitable for encapsulation.

The invention is concerned with perfume compositions, which are designed to be encapsulated in core-shell microcapsules. The invention also relates to encapsulated perfume compositions containing said core-shell microcapsules and their use in consumer products, such as household, laundry and personal care products.

Consumer products, such as household, laundry and personal care products, typically contain perfumes that are expected to deliver long-lasting and pleasant odours to substrates onto which they are applied. However, it is often not possible to achieve this goal if perfume is incorporated into such products in neat form, as so-called “free-oil”. For this reason, it is common to formulate perfume composition in the cores of core-shell microcapsules.

The advantages of encapsulating perfumes in this way are well known in the art. In particular, microcapsules can increase the stability and useful life of the encapsulated perfume ingredients; they can facilitate the manipulation, handling and storage of the encapsulated perfume compositions, and control the emanation of pleasant odours in time and space; and they can also isolate perfume ingredients from chemical attack of aggressive external media in which they are suspended.

However, it remains a matter of considerable difficulty for formulators to design core-shell microcapsules that possess the requisite barrier properties to protect the core contents from external media during manufacture and storage, and yet still permit release of the core contents at a desired time, in response to an external stimulus, such as the action of heat, moisture, chemical reactivity, or in response to mechanical disruption.

Core-shell microcapules, particularly those comprising aminoplast or gelatin shells, are somewhat permeable and allow their core contents to leak when suspended in aqueous media, and particularly aqueous media containing surfactants and/or solvents. Perfume ingredients tend to leak from the cores over time in a process of diffusion. This is particularly a problem in media containing unstructured surfactants, which promote leakage by solubilizing or incorporating perfume ingredients into micelles.

It is obviously not desirable that perfume is extracted prematurely from microcapsules, but at the same time the microcapsules should not be so strong and resistant to disruption that they do not release their contents other than in response to the application of excessively high mechanical forces.

Today's consumers increasingly measure the efficacy of a fragranced consumer product not only in terms of the perfume intensity in response physical force being applied to a treated substrate, such as skin, hair or fabrics (the so-called post-rub intensity), but also the fragrance perception before application of physical force (pre-rub intensity). Post-rub intensity might be desirable for sustained perfumery benefits, but up-front freshness and perfume intensity (pre-rub) is also desirable to ensure perfumery benefits are perceivable at all stages of application of a consumer product.

Improving perfume release from microcapsules has been addressed in the prior art by proposing rules for the selecting the most appropriate perfume ingredients to be encapsulated. For example, improved perfume delivery from capsules has been claimed for perfumes comprising large amounts of ingredients having high clogP values as illustrated in U.S. Pat. No. 5,500,138.

Similarly, WO99/65458 teaches perfume selection criteria based on the clogP values of said ingredients, amongst other parameters.

WO2004016234 suggests perfume ingredients having clog P values of 2.5 or greater should be used in high amounts, i.e. 80-90% by weight, for optimal performance.

In EP1533364 clogP is regarded as a key parameter in encapsulated perfume design. Preferred perfume ingredients should have clogP values of 3.3 or greater, more particularly 4 or greater and these ingredients should be used in high amounts, for example greater than 80%, more particularly greater than 90% by weight.

The applicant has found, however, that selecting perfume ingredients suitable for encapsulation based on a consideration of their clogP values neither accounts adequately for the leakage stability of microcapsules when suspended in media containing high levels of surfactants, nor for pre-rub perfume impact of said encapsulated perfume compositions.

There remains a need to provide encapsulated perfume compositions that can be stably incorporated into consumer products, particularly those containing high levels of unstructured surfactants, which are resistant to leakage during storage, and which can be deposited onto a substrate to provide a long-lasting fragrance impression.

After considerable research effort, the applicant has discovered means for selecting perfume ingredients, such that encapsulated perfume compositions containing said ingredients, when incorporated into consumer products, are resistant to leakage, and furthermore, when deposited onto a substratecan provide both pre-rub and post-rub perfume benefits.

In particular, the applicant has found that by employing perfume selection criteria set forth in this disclosure, it is possible to control both the permeability of perfume compositions through a microcapsule shell and the rate of diffusion of the perfume ingredients through the shell.

More specifically, the applicant has found that a critical parameter of perfume ingredient selection is the electron density distribution within a perfume ingredient, as reflected by the temperature-independent integral of the molecular iso-surface having electron density equal to

0.002 e/a₀ ³

wherein

e is the dimension-less electron charge and

a₀ is the Bohr radius of the hydrogen atom (a₀=5.2917720859×10⁻¹¹ m).

Employing Molecular Operating Environment chemical computational software (Version 2009, ex Chemical Computing Group, Canada, or later versions thereof, and optionally using the DDASSL RECON software plug-in (Rensselaer Polytechnic Institute, 2001-2003, or later versions thereof)), the value of this integral is given by the so-called RECON_VOLTAE quantum chemically derived descriptor. In particular, it was surprisingly found that the leakage of perfume ingredients through a microcapsule shell is considerably suppressed when the value of the molecular iso-surface integral of ingredients exceeds a certain value, more fully described herein below.

RECON VOLTAE is a parameter describing or expressing the topography of a molecule iso-surface that encloses a molecular space having an electron density that is equal to 0.002 e/a³ ₀.

Accordingly, the present invention provides in a first aspect a perfume composition adapted to be encapsulated in core-shell microcapsules, wherein said perfume composition contains perfume ingredients having known RECON_VOLTAE values larger than about 1200 Bohr³, more particularly larger than about 1540 Bohr³, and still more particularly larger than about 1750 Bohr³.

In another aspect of the present invention there is provided an encapsulated perfume composition comprising at least one core-shell microcapsule dispersed in a suspending medium, the core comprising perfume ingredients having known RECON_VOLTAE values larger than about 1200 Bohr³, more particularly larger than 1540 Bohr³, and more particularly still larger than about 1750 Bohr³.

In yet another aspect of the invention there is provided a consumer product, such as a household, laundry and personal care products disclosed herein, containing an encapsulated perfume composition as described herein.

Further aspects of the invention include methods of preparing encapsulated perfume compositions, said methods comprising the steps of mixing together perfume ingredients, selected in accordance with the perfume selection criteria set forth herein, and in the amounts and relative proportions set forth herein.

Further aspects of the invention also include encapsulated perfume compositions made according to the methods described herein.

Further aspects of the invention also include methods of forming consumer products, such as household, laundry and personal care products disclosed herein, comprising the step of incorporating into said consumer products encapsulated perfume compositions described herein and made according to methods described herein. Other aspects of the invention include methods of improving the resistance to leakage of encapsulated perfume compositions, said methods comprising the step of encapsulating perfume compositions that contain perfume ingredients selected in accordance with the perfume selection criteria set forth herein, and in the amounts and relative proportions set forth herein.

As used herein, the term “known” as it is used in relation to the RECON_VOLTAE values, or any of the other physico-chemical parameters described herein, means the values are known to a formulator of a perfume composition, or can be calculated in accordance with the teaching of the present invention.

In an embodiment of the present invention more than 70 wt %, in particular more than 80 wt %, and more particularly more than 90 wt % of the perfume ingredients contained the cores of said core-shell microcapsules have known RECON_VOLTAE values larger than about 1200 Bohr³.

In a more particular embodiment of the present invention more than 30 wt %, more particularly more than 35 wt %, and more particularly still, more than 40 wt % of the perfume ingredients contained in the cores of said core-shell microcapsules have known RECON_VOLTAE values larger than about 1540 Bohr³.

Those encapsulated perfume compositions in which more than 30 wt%, more particularly more than 35 wt %, and more particularly still, more than 40 wt% of the perfume ingredients contained in the microcapsule cores have known RECON_VOLTAE values larger than about 1540 Bohr³, are particularly suitable for incorporation in aggressive (extractive) media. These media include fabric softening or conditioning products containing quaternized ester surfactants (so-called “esterquats”) and non-ionic surfactants. They are particularly suitable for use in fabric softening or conditioning products containing un-structured surfactants. Un-structured surfactants are relatively free to extract perfume ingredients by forming micelles or vesicles around them, and thereby solubilizing them. They can be contrasted with “structured surfactants”, which are essentially immobilized in a structure, such as a liquid crystalline, generally lamellar phase (sometimes called “mesophases”) and are thus generally unavailable to form micelles or vesicles, and are far less aggressive or extractive as a result. Unstructured surfactant compositions are generally transparent. This can be contrasted with structure compositions, which generally are turbid, opaque or pearlescent.

Fabric softener or conditioner products are more fully described herein below.

Encapsulated perfume compositions in which more than 70 wt %, more particularly, more than 80 wt%, and more particularly still, more than 90 wt % of perfume ingredients in the microcapsule cores have known RECON_VOLTAE values larger than about 1750 Bohr³ form another embodiment of the present invention.

Encapsulated perfume compositions in which more than 70 wt %, more particularly, more than 80 wt%, and more particularly still, more than 90 wt % of perfume ingredients in the microcapsule cores have known RECON_VOLTAE values larger than about 1750 Bohr³ are particularly suitable for incorporation into very aggressive media, such as those found in shampoos and other personal cleansing compositions comprising high level of anionic, non-ionic and/or zwitterionic surfactants.

In accordance with a particular embodiment of the present invention, the encapsulated perfume compositions described herein are characterised in that they are comprised of at least 3 perfume ingredients, more particularly at least 5, still more particularly at least 7 and more particularly still at least 9 perfume ingredients having RECON_VOLTAE values larger than about 1200 Bohr³, or larger than about 1540 Bohr³ or larger than about 1750 Bohr³.

As used herein in relation to encapsulated perfume ingredients “wt %” refers to the concentration of a perfume ingredient or group of perfume ingredients, relative to the total amount of encapsulated perfume ingredients. Preferably, the microcapsule cores contain only perfume ingredients, however, it is contemplated that in addition to perfume ingredients, the contents of the cores may contain non-perfumery ingredients or excipients such as solvents or diluents. For example, certain perfume ingredients are provided as solutions or are diluted in suitable solvents, such as triethyl citrate “TEC”. In such cases, only the amount of perfume would contribute to the wt % calculation and not the solvent used to dissolve or dilute the perfume ingredient.

Such solvents or diluents are hydrophobic materials that are miscible in the perfume ingredients, and which have little or no odour in the quantities employed. Solvents commonly employed have high C log P values, for example greater than 6 and even greater than 10. Solvents include triglyceride oil, mono and diglycerides, mineral oil, silicone oil, diethyl phthalate, poly(alpha-olefins), castor oil and isopropyl myristate.

The microcapsule cores may also contain commonly employed adjuvants. The term “adjuvants” refers to ingredients that may affect the performance of a composition other than its hedonic performance. For example, an adjuvant may be an ingredient that acts as an aid to processing a perfume composition or consumer product containing said composition, or it may improve handling or storage of a perfume composition or consumer product. It might also be an ingredient that provides additional benefits such as imparting colour or texture. It might also be an ingredient that imparts light resistance or chemical stability to one or more ingredients contained in a perfume composition or consumer product. A detailed description of the nature and type of adjuvants commonly used in perfume compositions or consumer products cannot be exhaustive, but it has to be mentioned that said ingredients are well known to a person skilled in the art. Examples of adjuvants include surfactants and emulsifiers; viscosity and rheology modifiers; thickening and gelling agents; preservative materials; pigments, dyestuffs and colouring matters; extenders, fillers and reinforcing agents; stabilisers against the detrimental effects of heat and light, bulking agents, acidulants, buffering agents and antioxidants.

A comprehensive list of perfume ingredients available for selection in accordance with the present invention, as well as exicpients commonly used in perfumery, may be found in the perfumery literature, for example “Perfume & Flavor Chemicals”, S. Arctander (Allured Publishing, 1994), as well as later editions of this work, which are herein incorporated by reference.

By formulating perfume compositions in accordance with the known RECON_VOLTAE values set out herein, it is possible to form encapsulated perfume compositions characterized in that the microcapsules have a high resistance to extraction or leakage into external suspending media. Because of the low propensity to leakage, it is possible to form encapsulated perfume compositions that are characterized in that the microcapsules have a very high core to shell weight ratio.

Thus, in another aspect of the present invention, there is provided an encapsulated perfume composition as described herein, wherein the core to shell weight ratio of the microcapsules is about 90:10 at least, or more particularly 95:5 at least.

In yet another aspect of the invention there is provided a method of preparing an encapsulated perfume composition, wherein the core to shell weight ratio of the microcapsules is about 90:10 at least, or more particularly 95:5 at least, said method comprising the step of encapsulating a perfume composition containing perfume ingredients selected in accordance with the perfume selection criteria set forth herein, and in the amounts and relative proportions set forth herein.

Without wishing to be bound by theory, it is believed that the electron density distribution of a perfume ingredient, as reflected by its RECON_VOLTAE value, influences the way it diffuses or leaks through the shell. In particular, the diffusion of ingredients having RECON_VOLTAE values above the threshold values recited hereinabove, e.g. above about1200, is delayed, or even suppressed, relative to perfume ingredients having RECON_VOLTAE values below the given threshold value. It follows from the above that in order to provide encapsulated perfume compositions having desirable long-term stability in consumer products, particularly those that contain aggressive or extractive media, such as those found in personal cleansing compositions and laundry detergents, while still delivering perfume at a desired release rate after deposition onto a substrate, the encapsulated perfume composition should contain a certain amount of perfume ingredients having known RECON_VOLTAE values below the aforementioned 1200 threshold. These sub-threshold perfume ingredients will diffuse more readily from the microcapsules.

Possessed with the knowledge of the RECON_VOLTAE parameter, and the relationship of RECON_VOLTAE to both performance and stability of encapsulated perfume compositions, the skilled person is able to create suitable encapsulated perfume compositions, by balancing the proportions of both sub- and super-threshold perfume ingredients, which are designed to be both stable and performant when used in consumer products containing more or less extractive media.

Thus, an encapsulated perfume composition as defined hereinabove, additionally comprising encapsulated perfume ingredients having RECON_VOLTAE values below 1200 Bohr³, forms yet another aspect of the present invention.

In a particular embodiment of the present invention, the encapsulated perfume composition is characterized by a distribution of perfume ingredients having known RECON_VOLTAE values, wherein 70 wt % or more, more preferably 80 wt % or more, and most preferably 90 wt % or more of the perfume ingredients have known RECON_VOLTAE values larger than 1200 Bohr³ and 0.1 to 30 wt %, more particularly from 1 to 20 wt % and more particularly still from 1 to 10 wt % of perfume ingredients having known RECON_VOLTAE values below 1200 Bohr³.

In another embodiment of the present invention, the encapsulated perfume composition is characterized by a distribution of perfume ingredients having known RECON_VOLTAE values, wherein:

-   -   30 wt % or more, more particularly 35 wt % or more, and more         particularly 40 wt % or more of perfume ingredients have known         RECON_VOLTAE values larger than 1540 Bohr³;     -   20 to 60 wt %, more particularly 25 to 50 wt % and more         particularly still 30 to 40 wt % of the perfume ingredients have         known RECON_VOLTAE values from 1200 Bohr³ to 1540 Bohr³; and     -   0.1 to 30 wt %, more particularly from 1 to 20 wt % and more         particularly still, from 1 to 10 wt% of the perfume ingredients         have known RECON_VOLTAE values below 1200 Bohr³.

In yet another embodiment of the present invention, the encapsulated perfume composition is characterized by a distribution of perfume ingredients having known RECON_VOLTAE values, wherein:

-   -   from 0.5 to 30 wt %, more particularly from 1 to 25 wt %, and         more particularly still from to 20 wt % of the perfume         ingredients have known RECON_VOLTAE values above 1750 Bohr³     -   20 to 60 wt %, more particularly 25 to 55 wt % or more, more         particularly still from 30 to 50 wt % or more of the perfume         ingredients having known RECON_VOLTAE values from 1540 Bohr³ to         1750 Bohr ³; and     -   5 to 50 wt % or more, more particularly 10 to 40 wt % or more         particularly still 15 to 30 wt % or more of the perfume         ingredients have known RECON_VOLTAE values from 1200 Bohr³ to         1540 Bohr³; and     -   0.1 to 30 wt %, more particularly from 1 to 20 wt % and more         particularly still from 1 to 10 wt % of perfume ingredients have         known RECON_VOLTAE values below 1200 Bohr³.

In yet another embodiment of the present invention, the encapsulated perfume composition is characterized by a distribution of perfume ingredients having known RECON_VOLTAE values, wherein 70 wt % or more, more preferably 80 wt % or more, and most preferably 90 wt % or more of perfume ingredients have known RECON_VOLTAE values larger than 1750 Bohr³; and 0.1 to 30 wt %, more particularly from 1 to 20 wt % and more particularly still from 1 to 10 wt % of the perfume ingredients have known RECON_VOLTAE values below 1750 Bohr³.

Preferably, the weight average known RECON_VOLTAE values of the perfume ingredients of encapsulated perfume compositions of the present invention should be larger than 1540 Bohr³ and more particularly larger than 1750 Bohr³.

The weight average of known RECON_VOLTAE values is defined here as the weighed algebraic mean of the ingredient known RECON_VOLTAE values divided by the number of ingredients:

${\langle{RECON\_ VOLTAE}\rangle}_{perfume} \equiv {{1/n}{\sum\limits_{n}\; {\left( \%_{i} \right)\left( {RECON\_ VOLTAE}_{i} \right)}}}$

wherein n is the number of ingredients i, % the weight percentage of ingredient i and RECON_VOLTAE_(i), the RECON_VOLTAE value of ingredient i.

Particularly stable and performant encapsulated perfume compositions can be prepared, when the selection of perfume ingredients is made on the basis of both the RECON_VOLTAE parameter as described hereinabove, and according to a perfume ingredient's equilibrium headspace-capsule partition coefficient “Kcaps” The equilibrium headspace-capsule partition coefficient is defined as the headspace concentration (HS_(i) ^(e)) of a perfume ingredient i in equilibrium with a microcapsule containing an encapsulated perfume composition P comprising perfume ingredient i at a given concentration divided by the headspace concentration (HS_(i) ^(p)) in equilibrium with free perfume P comprising same concentration of ingredient i.

${Kcaps}_{i} = \frac{{HS}_{i}^{c}}{{HS}_{i}^{p}}$

The headspace concentration in equilibrium with a microcapsule can be measured using techniques well known to a person skilled in the art. In a typical procedure, an encapsulated perfume composition containing a known concentration of microcapsules is transferred to a vial VC, which is closed with a septum and allowed to equilibrate at 25° C., and a known amount of free perfume is transferred to a vial VP containing a strip of blotter paper on which the perfume is deposited with a syringe. The vial is closed with a septum and allowed to equilibrate at 25° C. Headspace aliquots are then taken from both vials and the headspace concentration profiles are determined quantitatively using methods known in the art, such as headspace capillary gas chromatography, headspace gas chromatography ion mobility spectrometry, gas spectroscopy and the like.

Kcaps may be determined experimentally, or it can be calculated for an ingredient using techniques known in the art. In particular, the effect of perfume ingredients on microcapsule stability can be predicted from QSAR analysis using MOE software.

As the person skilled in the art will appreciate, QSAR methods, in the context of the present invention, assume that performance of a perfume ingredient is correlated with its chemical structure and that as a consequence activity can be modeled as a function of calculable physiochemical attributes. Such a model for performance prediction can then be used to screen the palette of known perfume ingredients, or indeed libraries of other molecules for useful candidate ingredients.

Using QSAR analysis of a representative sample of perfume ingredients in the present invention resulted in the identification of a physicochemical parameter (log₁₀ Kcaps) contributing to the effect of perfume ingredients on the stability of microcapsules.

Log₁₀Kcaps was calculated by constructing a Quantitative Structure Activity Relationship, by performing a linear regression of molecular descriptors available within computational chemistry perfume MOE (Molecular Operation Environment, version 2013.08.01, purchased from Chemical Computing Group, Corporate Headquarters, 1010 Sherbrooke St. W, Suite 910, Montreal, Canada H3A 2R7, optionally using the DDASSL RECON software plug-in (Rensselaer Polytechnic Institute, 2001-2003, or later versions thereof)). QSAR analysis was carried out using a total of 75 perfume ingredients selected for the analysis on the basis of them being a representative set of perfume ingredients that had been used in encapsulated perfume compositions. The resulting QSAR equation is given below:

Log₁₀ Kcaps=−0.613884945931533+0.367145678964078 Average_EO_Neg+0.154423533060832 E_sol+1.72305610065098 MACCS(136)+0.0650007063247245 PEOE_VSA+3−1.6045990231291 PEOE_VSA_FPOS +12.0572868318683 RA_2D_pEP10−1082.58386145862 RA_nEP2−0.0382420195399682 RECON_Del(K)NA3+53.5822360317755 RECON_FEP9−2.50813850930136 RECON_FPIP8+5.73871249195905 RECON_SIKA10+0.0400054462330909 kS_tsC

The definition of the molecular descriptors used in above equation can be found in MOE manual version 2013.08.01 (edited by Molecular Operation Environment, Chemical Computing Group, Corporate Headquarters, 1010 Sherbrooke St. W, Suite 910, Montreal, Canada H3A 2R7); or R. Todeschini and V. Consonni, Handbook of Molecular Descriptors, Wiley, 2000; and DDASSL RECON manual (Rensselaer Polytechnic Institute, 2001-2003, or later versions thereof).

Calculated Log₁₀ Kcaps values of some perfume ingredients are provided in the Tables below.

Perfume ingredients that are particularly useful in encapsulated perfume compositions according to the present invention may be grouped according to their respective RECON_VOLTAE values and their calculated log₁₀ Kcaps values.

Thus, GROUP 1 perfume ingredients have RECON_VOLTAE values larger than 1200 Bohr³ and calculated log₁₀ Kcaps which are greater than −3, where the term log₁₀ refers to the decimal logarithm. Perfume ingredients of GROUP 1 include but are not limited to

RECON_VOLTAE Perfumery ingredient (Bohr3) LogKcaps HEDIONE (methyl 3-oxo-2- 1784 −2.4 pentylcyclopentaneacetate) ALLYL CYCLOHEXYL PROPIONATE (allyl 1606 −2.0 3-cyclohexylpropanoate) AGRUMEX (2-(tert-butyl)cyclohexyl acetate) 1678 −1.9 DIMETHYL BENZYL CARBINYL ACETATE 1506 −2.4 (2-methyl-1-phenylpropan-2-yl acetate) IRISONE ALPHA ((E)-4-(2,6,6- 1676 −1.8 trimethylcyclohex-2-en-1-yl)but-3-en-2-one) ISO E SUPER (1-(2,3,8,8-tetramethyl- 2024 −1.4 1,2,3,4,5,6,7,8-octahydronaphthalen-2- yl)ethanone) ISORALDEINE 70 ((E)-3-methyl-4-(2,6,6- 1806 −2.0 trimethylcyclohex-2-en-1-yl)but-3-en-2-one) NECTARYL (2-(2-(4-methylcyclohex-3-en-1- 1822 −1.9 yl)propyl)cyclopentanone) BOISAMBRENE FORTE 2063 −2.0 ((ethoxymethoxy)cyclododecane) BOISIRIS ((1S,2R,5R)-2-ethoxy-2,6,6- 1914 −1.0 trimethyl-9-methylenebicyclo[3.3.1]nonane) JASMACYCLENE ((3aR,6S,7aS)- 1418 −1.7 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden- 6-yl acetate) FLOROCYCLENE ((3aR,6S,7aS)- 1549 −1.6 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden- 6-yl propionate) HEXYL SALICYLATE (hexyl 2- 1685 −1.6 hydroxybenzoate) DIPENTENE (1-methyl-4-(prop-1-en-2- 1203 −0.1 yl)cyclohex-1-ene) TETRAHYDRO LINALOOL (3,7- 1449 −2.2 dimethyloctan-3-ol) AMYL SALICYLATE (pentyl 2- 1556 −1.4 hydroxybenzoate) ALDEHYDE C 12 MNA PURE (2- 1661 −2.3 methylundecanal) BUTYL CYCLOHEXYL ACETATE PARA (4- 1682 −2.7 (tert-butyl)cyclohexyl acetate) DAMASCONE DELTA ((E)-1-(2,6,6- 1654 −1.3 trimethylcyclohex-3-en-1-yl)but-2-en-1-one) DIMETHYL BENZYL CARBINYL 1767 −1.6 BUTYRATE (2-methyl-1-phenylpropan-2-yl butyrate) EUCALYPTOL ((1s,4s)-1,3,3-trimethyl-2- 1278 −1.0 oxabicyclo[2.2.2]octane) FRUTONILE (2-methyldecanenitrile) 1597 −1.9 HEXYL CINNAMIC ALDEHYDE ((E)-2- 1778 −2.5 benzylideneoctanal) IONONE BETA ((E)-4-(2,6,6- 1670 −1.6 trimethylcyclohex-1-en-1-yl)but-3-en-2-one) TERPINYL ACETATE (2-(4-methylcyclohex- 1590 −2.0 3-en-1-yl)propan-2-yl acetate) UNDECAVERTOL ((E)-4-methyldec-3-en-5- 1531 −2.1 ol) LINALOOL (3,7-dimethylocta-1,6-dien-3-ol) 1367 −2.3 GARDOCYCLENE ((3aR,6S,7aS)- 1677 −1.5 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden- 6-yl isobutyrate) IRISONE ((E)-4-(2,6,6-trimethylcyclohex-2-en- 1676 −1.8 1-yl)but-3-en-2-one) LILIAL (3-(4-(tert-butyl)phenyl)-2- 1738 −2.0 methylpropanal) LINALYL ACETATE (3,7-dimethylocta-1,6- 1653 −1.5 dien-3-yl acetate) GERANIOL ((E)-3,7-dimethylocta-2,6-dien-1- 1357 −2.0 ol) ALLYL OENANTHATE (allyl heptanoate) 1436 −2.5 PETALIA (2-cyclohexylidene-2-(o- 1753 −1.4 tolyl)acetonitrile) NEOBERGAMATE FORTE (2-methyl-6- 1650 −1.4 methyleneoct-7-en-2-yl acetate) ISONONYL ACETATE (3,5,5-trimethylhexyl 1632 −1.0 acetate) FRESKOMENTHE (2-(sec- 1313 −1.6 butyl)cyclohexanone) ORIVONE (4-(tert-pentyl)cyclohexanone) 1474 −2.1 NONADYL (6,8-dimethylnonan-2-ol) 1579 −1.8 METHYL PAMPLEMOUSSE (6,6-dimethoxy- 1632 −1.9 2,5,5-trimethylhex-2-ene) ETHYL CAPRYLATE (ethyl octanoate) 1462 −1.5 AMBER CORE (1-((2-(tert- 1972 −2.3 butyl)cyclohexyl)oxy)butan-2-ol) CASHMERAN (1,1,2,3,3-pentamethyl-2,3,6,7- 1772 −1.9 tetrahydro-1H-inden-4(5H)-one) CITRONELLOL (3,7-dimethyloct-6-en-1-ol) 1392 −2.4 DAMASCENONE ((E)-1-(2,6,6- 1608 −1.5 trimethylcyclohexa-1,3-dien-1-yl)but-2-en-1- one) ETHYL SAFRANATE (ethyl 2,6,6- 1579 −2.0 trimethylcyclohexa-1,3-diene-1-carboxylate) EUCALYPTOL ((1s,4s)-1,3,3-trimethyl-2- 1278 −1.0 oxabicyclo[2.2.2]octane) PEONILE (2-cyclohexylidene-2- 1633 −0.9 phenylacetonitrile) DELPHONE (2-pentylcyclopentanone) 1313 −1.9 SILVIAL (3-(4-isobutylphenyl)-2- 1700 −2.5 methylpropanal) TETRAHYDRO MYRCENOL (2,6- 1449 −2.1 dimethyloctan-2-ol) CITRONELLYL PROPIONATE (3,7- 1808 −2.0 dimethyloct-6-en-1-yl propionate) CYCLOHEXYL SALICYLATE (cyclohexyl 2- 1610 −2.2 hydroxybenzoate) ETHYL CAPROATE (ethyl hexanoate) 1203 −1.4 CORANOL (4-cyclohexyl-2-methylbutan-2-ol) 1486 −2.7 BORNYL ACETATE ((2S,4S)-1,7,7- 1631 −1.8 trimethylbicyclo[2.2.1]heptan-2-yl acetate) ALDEHYDE C 10 DECYLIC (decanal) 1403 −2.9 ALDEHYDE C 110 UNDECYLIC (undecanal) 1533 −2.8 ALDEHYDE MANDARINE 10%/TEC ((E)- 1615 −2.7 dodec-2-enal) AMBERMAX (1,3,4,5,6,7-hexahydro- 2275 −2.8 .beta.,1,1,5,5-pentamethyl-2H-2,4a- Methanonaphthalene-8-ethanol) BELAMBRE ((1R,2S,4R)-2′-isopropyl-1,7,7- 2112 −1.6 trimethylspiro[bicyclo[2.2.1]heptane-2,4′- [1,3]dioxane]) CITRONELLYL NITRILE (3,7-dimethyloct-6- 1429 −1.6 enenitrile) FLORHYDRAL (3-(3-isopropylphenyl)butanal) 1568 −2.7 GERANYL ACETATE SYNTHETIC ((E)-3,7- 1643 −2.4 dimethylocta-2,6-dien-1-yl acetate) HABANOLIDE ((E)-oxacyclohexadec-12-en-2- 1978 −2.6 one) HEXYL ISOBUTYRATE (hexyl isobutyrate) 1460 −1.0 MYRALDENE (4-(4-methylpent-3-en-1- 1613 −2.2 yl)cyclohex-3-enecarbaldehyde) TRIDECENE-2-NITRILE ((E)-tridec-2- 1818 −1.5 enenitrile) ROSACETOL (2,2,2-trichloro-1-phenylethyl 1731 −1.5 acetate) CITRONELLYL ACETATE (3,7-dimethyloct- 1678 −1.7 6-en-1-yl acetate) ETHYL LINALOOL ((E)-3,7-dimethylnona- 1497 −2.1 1,6-dien-3-ol) DIPENTENE (1-methyl-4-(prop-1-en-2- 1203 −0.1 yl)cyclohex-1-ene) GERANYL ISOBUTYRATE ((E)-3,7- 1901 −1.2 dimethylocta-2,6-dien-1-yl isobutyrate) ISOPROPYL METHYL-2-BUTYRATE 1212 −1.1 (isopropyl 2-methyl butanoate) RADJANOL SUPER ((E)-2-ethyl-4-(2,2,3- 1829 −2.3 trimethylcyclopent-3-en-1-yl)but-2-en-1-ol) TERPINOLENE (1-methyl-4-(propan-2- 1204 −0.1 ylidene)cyclohex-1-ene) ETHYL LINALYL ACETATE ((Z)-3,7- 1783 −1.1 dimethylnona-1,6-dien-3-yl acetate) SERENOLIDE (2-(1-(3,3- 2429 −2.0 dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate) CITRAL ((E)-3,7-dimethylocta-2,6-dienal) 1311 −1.8 DIMETHYL OCTENONE (4,7-dimethyloct-6- 1360 −0.8 en-3-one) GALBANONE PURE (1-(3,3- 1663 −1.9 dimethylcyclohex-1-en-1-yl)pent-4-en-1-one) KOAVONE ((Z)-3,4,5,6,6-pentamethylhept-3- 1675 −1.6 en-2-one) NEROLIDYLE ((Z)-3,7,11-trimethyldodeca- 2257 −2.3 1,6,10-trien-3-yl acetate) ADOXAL (2,6,10-trimethylundec-9-enal) 1878 −2.5 MENTHOL NATURAL (2-isopropyl-5- 1357 −2.1 methylcyclohexanol) ALDEHYDE C 12 LAURIC (dodecanal) 1662 −2.9 CITRONELLAL (3,7-dimethyloct-6-enal) 1363 −2.4 COSMONE ((Z)-3-methylcyclotetradec-5- 1924 −2.5 enone) CYCLAMEN ALDEHYDE (3-(4- 1567 −1.6 isopropylphenyl)-2-methylpropanal) DIMETHYL BENZYL CARBINOL (2-methyl- 1223 −2.4 1-phenylpropan-2-ol) FLORALOZONE (3-(4-ethylphenyl)-2,2- 1608 −1.9 dimethylpropanal) HERBANATE ((2S)-ethyl 3- 1629 −0.7 isopropylbicyclo[2.2.1]hept-5-ene-2- carboxylate) LEMONILE ((2E,6Z)-3,7-dimethylnona-2,6- 1515 −1.5 dienenitrile) DIMETOL (2,6-dimethylheptan-2-ol) 1320 −2.0 PIVAROSE (2,2-dimethyl-2-pheylethyl 1665 −2.5 propanoate) PRECYCLEMONE B (1-methyl-4-(4- 1783 −2.2 methylpent-3-en-1-yl)cyclohex-3- enecarbaldehyde) CITRONELLYL ACETATE (3,7-dimethyloct- 1678 −1.7 6-en-1-yl acetate) ALDEHYDE C 11 UNDECYLENIC (undec- 1498 −2.9 10-enal) ETHYL OENANTHATE (ethyl heptanoate) 1333 −1.5 KARANAL (5-(sec-butyl)-2-(2,4- 2242 −1.4 dimethylcyclohex-3-en-1-yl)-5-methyl-1,3- dioxane) NERYL ACETATE HC ((Z)-3,7-dimethylocta- 1643 −2.4 2,6-dien-1-yl acetate) THIBETOLIDE (oxacyclohexadecan-2-one) 2017 −2.2 FLOROPAL (2,4,6-trimethyl-4-phenyl-1,3- 1596 −1.1 dioxane) GIVESCONE (ethyl 2-ethyl-6,6- 1754 −1.5 dimethylcyclohex-2-enecarboxylate) TERPINENE GAMMA (1-methyl-4-propan-2- 1205 −0.4 ylcyclohexa-1,4-diene) FIXOLIDE (1-(3,5,5,6,8,8-hexamethyl-5,6,7,8- 2207 −2.2 tetrahydronaphthalen-2-yl)ethanone) CITRAL LEMAROME N ((E)-3,7- 1311 −2.1 dimethylocta-2,6-dienal) METHYL CEDRYL KETONE (1-((1S,8aS)- 2076 −1.9 1,4,4,6-tetramethyl-2,3,3a,4,5,8-hexahydro-1H- 5,8a-methanoazulen-7-yl)ethanone) PARADISAMIDE (2-ethyl-N-methyl-N-(m- 1790 −3.0 tolyl)butanamide) RASPBERRY KETONE (N112) (4-(4- 1243 −2.4 hydroxyphenyl)butan-2-one) ROSYRANE SUPER (4-methylene-2- 1353 −1.8 phenyltetrahydro-2H-pyran) NEOFOLIONE ((E)-methyl non-2-enoate) 1418 −2.1 APHERMATE (1-(3,3- 1549 −1.9 dimethylcyclohexyl)ethyl formate) CARYOPHYLLENE ((Z)-4,11,11-trimethyl-8- 1809 −1.0 methylenebicyclo[7.2.0]undec-4-ene) STEMONE ((E)-5-methylheptan-3-one oxime) 1250 −1.7 EBANOL ((E)-3-methyl-5-(2,2,3- 1832 −2.5 trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol) CYCLOMYRAL (8,8-dimethyl-1,2,3,4,5,6,7,8- 1610 −2.4 octahydronaphthalene-2-carbaldehyde) FENCHYL ACETATE ((2S)-1,3,3- 1628 −2.2 trimethylbicyclo[2.2.1]heptan-2-yl acetate) JASMONE CIS ((Z)-3-methyl-2-(pent-2-en-1- 1379 −1.7 yl)cyclopent-2-enone) METHYL NONYL KETONE EXTRA 1532 −1.8 (undecan-2-one) SYLKOLIDE ((E)-2-((3,5-dimethylhex-3-en-2- 2177 −1.9 yl)oxy)-2-methylpropyl cyclopropanecarboxylate) MELONAL (2,6-dimethylhept-5-enal) 1229 −2.0 BUTYL BUTYRO LACTATE (1-butoxy-1- 1680 −0.1 oxopropan-2-yl butyrate) ALDEHYDE ISO C 11 ((E)-undec-9-enal) 1491 −3.0 DAMASCENONE GIV ((E)-1-(2,6,6- 1608 −1.5 trimethylcyclohexa-1,3-dien-1-yl)but-2-en-1- one) ROSALVA (dec-9-en-1-ol) 1397 −2.6 VIRIDINE ((2,2-dimethoxyethyl)benzene) 1281 −2.7 FRUITATE ((3aS,4S,7R,7aS)-ethyl octahydro- 1617 −1.1 1H-4,7-methanoindene-3a-carboxylate) CITRONELLYL FORMATE (3,7-dimethyloct- 1544 −1.9 6-en-1-yl formate) EUCALYPTOL ((1s,4s)-1,3,3-trimethyl-2- 1278 −1.0 oxabicyclo[2.2.2]octane) IRONE ALPHA ((E)-4-(2,5,6,6- 1800 −1.5 tetramethylcyclohex-2-en-1-yl)but-3-en-2-one) MENTHONE (2-isopropyl-5- 1312 −1.4 methylcyclohexanone) HEXENYL-3-CIS BUTYRATE ((Z)-hex-3-en- 1421 −1.2 1-yl butyrate) ALDEHYDE C 11 MOA (2-methyldecanal) 1530 −2.6 CLONAL (dodecanenitrile) 1723 −1.0 DAMASCONE ALPHA ((E)-1-(2,6,6- 1657 −1.1 trimethylcyclohex-2-en-1-yl)but-2-en-1-one) DECENAL-4-TRANS ((E)-dec-4-enal) 1363 −2.8 DUPICAL ((E)-4-((3aS,7aS)-hexahydro-1H- 1607 −2.5 4,7-methanoinden-5(6H)-ylidene)butanal) FENCHYL ALCOHOL ((1S,2R,4R)-1,3,3- 1345 −2.0 trimethylbicyclo[2.2.1]heptan-2-ol) INDOFLOR (4,4a,5,9b-tetrahydroindeno[1,2- 1245 −2.7 d][1,3]dioxine) MALTYL ISOBUTYRATE (2-methyl-4-oxo- 1398 −0.1 4H-pyran-3-yl isobutyrate) METHYL OCTYNE CARBONATE (methyl 1376 −1.8 non-2-ynoate) PELARGENE (2-methyl-4-methylene-6- 1480 −1.5 phenyltetrahydro-2H-pyran) PYRALONE (6-(sec-butyl)quinoline) 1466 −1.8 SUPER MUGUET ((E)-6-ethyl-3-methyloct-6- 1522 −2.7 en-1-ol) VELOUTONE (2,2,5-trimethyl-5- 1778 −1.9 pentylcyclopentanone) RHUBAFURANE (2,2,5-trimethyl-5- 1434 −1.9 pentylcyclopentanone) SPIROGALBANONE (1-(spiro[4.5]dec-6-en-7- 1850 −2.0 yl)pent-4-en-1-one) DIHYDRO ANETHOLE (propanedioic acid 1- 1219 −1.7 (1-(3,3-dimethylcyclohexyl)ethyl) 3-ethyl ester) ZINARINE (2-(2,4- 1557 −2.1 dimethylcyclohexyl)pyridine) BIGARYL (8-(sec-butyl)-5,6,7,8- 1563 −2.0 tetrahydroquinoline) CASSYRANE (5-tert-butyl-2-methyl-5-propyl- 1624 −1.6 2H-furan) MANZANATE (ethyl 2-methylpentanoate) 1202 −1.4 NONENAL-6-CIS ((Z)-non-6-enal) 1234 −2.5 ALLYL AMYL GLYCOLATE (allyl 2- 1495 −2.2 (isopentyloxy)acetate) DIHYDRO JASMONE (3-methyl-2- 1409 −1.7 pentylcyclopent-2-enone) ISOCYCLOCITRAL (2,4,6-trimethylcyclohex- 1266 −1.8 3-enecarbaldehyde) LEAF ACETAL ((Z)-1-(1-ethoxyethoxy)hex-3- 1457 −0.7 ene) CYCLOGALBANATE (allyl 2- 1546 −2.4 (cyclohexyloxy)acetate) LIFFAROME GIV ((Z)-hex-3-en-1-yl methyl 1218 −1.5 carbonate) CITRATHAL R ((Z)-1,1-diethoxy-3,7- 1933 −1.1 dimethylocta-2,6-diene) ROSYFOLIA ((1-methyl-2-(5-methylhex-4-en- 1685 −1.0 2-yl)cyclopropyl)-methanol) (3-(4-isobutyl-2-methylphenyl)propanal) 1700 −2.5

When encapsulated in the amounts referred to hereinabove in accordance with the present invention, encapsulated perfume compositions containing perfume ingredients of GROUP 1 exhibit superior resistance to leakage when suspended in mildly extractive media, such as those encountered in fabric softener or conditioning compositions, and particularly those compositions containing structured surfactants.

Those encapsulated perfume compositions described hereinabove containing perfume ingredients characterized by a RECON_VOLTAE value larger than about 1200 Bohr³, wherein those ingredients are additionally characterized by a log₁₀ Kcaps greater than −3 (i.e. GROUP 1 ingredients) form additional embodiments of the present invention.

Furthermore, fabric softener or conditioning compositions, particularly those containing structured surfactants, containing said encapsulated perfume compositions form further embodiments of the present invention.

A second group of perfume ingredients, so called GROUP 2 ingredients, have RECON_VOLTAE values larger than 1540 Bohr³ and log₁₀ Kcaps greater than −3. Perfume ingredients of GROUP 2 include but are not limited to

RECON_VOLTAE Perfumery ingredient (Bohr3) LogKcaps HEDIONE (methyl 3-oxo-2- 1784 −2.4 pentylcyclopentaneacetate) ALLYL CYCLOHEXYL PROPIONATE 1606 −2.0 (allyl 3-cyclohexylpropanoate) AGRUMEX (2-(tert-butyl)cyclohexyl 1678 −1.9 acetate) IRISONE ALPHA ((E)-4-(2,6,6- 1676 −1.8 trimethylcyclohex-2-en-1-yl)but-3-en-2-one) ISO E SUPER (1-(2,3,8,8-tetramethyl- 2024 −1.4 1,2,3,4,5,6,7,8-octahydronaphthalen-2- yl)ethanone) ISORALDEINE 70 ((E)-3-methyl-4-(2,6,6- 1806 −2.0 trimethylcyclohex-2-en-1-yl)but-3-en-2-one) NECTARYL (2-(2-(4-methylcyclohex-3-en- 1822 −1.9 1-yl)propyl)cyclopentanone) BOISAMBRENE FORTE 2063 −2.0 ((ethoxymethoxy)cyclododecane) BOISIRIS ((1S,2R,5R)-2-ethoxy-2,6,6- 1914 −1.0 trimethyl-9-methylenebicyclo[3.3.1]nonane) FLOROCYCLENE ((3aR,6S,7aS)- 1549 −1.6 3a,4,5,6,7,7a-hexahydro-1H-4,7- methanoinden-6-yl propionate) HEXYL SALICYLATE (hexyl 2- 1685 −1.6 hydroxybenzoate) ALDEHYDE C 12 MNA PURE (2- 1661 −2.3 methylundecanal) BUTYL CYCLOHEXYL ACETATE PARA 1682 −2.7 (4-(tert-butyl)cyclohexyl acetate) DAMASCONE DELTA ((E)-1-(2,6,6- 1654 −1.3 trimethylcyclohex-3-en-1-yl)but-2-en-1-one) DIMETHYL BENZYL CARBINYL 1767 −1.6 BUTYRATE (2-methyl-1-phenylpropan-2-yl butyrate) HEXYL CINNAMIC ALDEHYDE ((E)-2- 1778 −2.5 benzylideneoctanal) IONONE BETA ((E)-4-(2,6,6- 1670 −1.6 trimethylcyclohex-1-en-1-yl)but-3-en-2-one) TERPINYL ACETATE (2-(4- 1590 −2.0 methylcyclohex-3-en-1-yl)propan-2-yl acetate) GARDOCYCLENE ((3aR,6S,7aS)- 1677 −1.5 3a,4,5,6,7,7a-hexahydro-1H-4,7- methanoinden-6-yl isobutyrate) IRISONE PURE ((E)-4-(2,6,6- 1676 −1.8 trimethylcyclohex-2-en-1-yl)but-3-en-2-one) LILIAL (3-(4-(tert-butyl)phenyl)-2- 1738 −2.0 methylpropanal) LINALYL ACETATE SYNTHETIC (3,7- 1653 −1.5 dimethylocta-1,6-dien-3-yl acetate) PETALIA (2-cyclohexylidene-2-(o- 1753 −1.4 tolyl)acetonitrile) NEOBERGAMATE FORTE (2-methyl-6- 1650 −1.4 methyleneoct-7-en-2-yl acetate) ISONONYL ACETATE PURE (3,5,5- 1632 −1.0 trimethylhexyl acetate) NONADYL (6,8-dimethylnonan-2-ol) 1579 −1.8 METHYL PAMPLEMOUSSE (6,6- 1632 −1.9 dimethoxy-2,5,5-trimethylhex-2-ene) AMBER CORE (1-((2-(tert- 1972 −2.3 butyl)cyclohexyl)oxy)butan-2-ol) CASHMERAN (1,1,2,3,3-pentamethyl- 1772 −1.9 2,3,6,7-tetrahydro-1H-inden-4(5H)-one) DAMASCENONE ((E)-1-(2,6,6- 1608 −1.5 trimethylcyclohexa-1,3-dien-1-yl)but-2-en-1- one) ETHYL SAFRANATE (ethyl 2,6,6- 1579 −2.0 trimethylcyclohexa-1,3-diene-1-carboxylate) PEONILE (2-cyclohexylidene-2- 1633 −0.9 phenylacetonitrile) SILVIAL (3-(4-isobutylphenyl)-2- 1700 −2.5 methylpropanal) CITRONELLYL PROPIONATE (3,7- 1808 −2.0 dimethyloct-6-en-1-yl propionate) CYCLOHEXYL SALICYLATE (cyclohexyl 1610 −2.2 2-hydroxybenzoate) BORNYL ACETATE ((2S,4S)-1,7,7- 1631 −1.8 trimethylbicyclo[2.2.1]heptan-2-yl acetate) ALDEHYDE MANDARINE ((E)-dodec-2- 1615 −2.7 enal) AMBERMAX (1,3,4,5,6,7-hexahydro- 2275 −2.8 .beta.,1,1,5,5-pentamethyl-2H-2,4a- Methanonaphthalene-8-ethanol) BELAMBRE 50%/IPM ((1R,2S,4R)-2′- 2112 −1.6 isopropyl-1,7,7- trimethylspiro[bicyclo[2.2.1]heptane-2,4′- [1,3]dioxane]) FLORHYDRAL (3-(3- 1568 −2.7 isopropylphenyl)butanal) GERANYL ACETATE SYNTHETIC ((E)- 1643 −2.4 3,7-dimethylocta-2,6-dien-1-yl acetate) HABANOLIDE ((E)-oxacyclohexadec-12- 1978 −2.6 en-2-one) MYRALDENE (4-(4-methylpent-3-en-1- 1613 −2.2 yl)cyclohex-3-enecarbaldehyde) TRIDECENE-2-NITRILE ((E)-tridec-2- 1818 −1.5 enenitrile) ROSACETOL (2,2,2-trichloro-1-phenylethyl 1731 −1.5 acetate) CITRONELLYL ACETATE (3,7- 1678 −1.7 dimethyloct-6-en-1-yl acetate) GERANYL ISOBUTYRATE ((E)-3,7- 1901 −1.2 dimethylocta-2,6-dien-1-yl isobutyrate) RADJANOL SUPER ((E)-2-ethyl-4-(2,2,3- 1829 −2.3 trimethylcyclopent-3-en-1-yl)but-2-en-1-ol) ETHYL LINALYL ACETATE ((Z)-3,7- 1783 −1.1 dimethylnona-1,6-dien-3-yl acetate) SERENOLIDE (2-(1-(3,3- 2429 −2.0 dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate) GALBANONE PURE (1-(3,3- 1663 −1.9 dimethylcyclohex-1-en-1-yl)pent-4-en-1-one) KOAVONE ((Z)-3,4,5,6,6-pentamethylhept- 1675 −1.6 3-en-2-one) NEROLIDYLE ((Z)-3,7,11-trimethyldodeca- 2257 −2.3 1,6,10-trien-3-yl acetate) ADOXAL (2,6,10-trimethylundec-9-enal) 1878 −2.5 ALDEHYDE C 12 LAURIC (dodecanal) 1662 −2.9 COSMONE ((Z)-3-methylcyclotetradec-5- 1924 −2.5 enone) CYCLAMEN ALDEHYDE (3-(4- 1567 −1.6 isopropylphenyl)-2-methylpropanal) FLORALOZONE (3-(4-ethylphenyl)-2,2- 1608 −1.9 dimethylpropanal) HERBANATE ((2S)-ethyl 3- 1629 −0.7 isopropylbicyclo[2.2.1]hept-5-ene-2- carboxylate) PIVAROSE (2,2-dimethyl-2-pheylethyl 1665 −2.5 propanoate) PRECYCLEMONE B (1-methyl-4-(4- 1783 −2.2 methylpent-3-en-1-yl)cyclohex-3- enecarbaldehyde) CITRONELLYL ACETATE (3,7- 1678 −1.7 dimethyloct-6-en-1-yl acetate) KARANAL (5-(sec-butyl)-2-(2,4- 2242 −1.4 dimethylcyclohex-3-en-1-yl)-5-methyl-1,3- dioxane) NERYL ACETATE HC ((Z)-3,7- 1643 −2.4 dimethylocta-2,6-dien-1-yl acetate) THIBETOLIDE (oxacyclohexadecan-2-one) 2017 −2.2 FLOROPAL (2,4,6-trimethyl-4-phenyl-1,3- 1596 −1.1 dioxane) GIVESCONE (ethyl 2-ethyl-6,6- 1754 −1.5 dimethylcyclohex-2-enecarboxylate) FIXOLIDE (1-(3,5,5,6,8,8-hexamethyl- 2207 −2.2 5,6,7,8-tetrahydronaphthalen-2-yl)ethanone) METHYL CEDRYL KETONE (1-((1S,8aS)- 2076 −1.9 1,4,4,6-tetramethyl-2,3,3a,4,5,8-hexahydro- 1H-5,8a-methanoazulen-7-yl)ethanone) PARADISAMIDE (2-ethyl-N-methyl-N-(m- 1790 −3.0 tolyl)butanamide) CARYOPHYLLENE ((Z)-4,11,11-trimethyl- 1809 −1.0 8-methylenebicyclo[7.2.0]undec-4-ene) EBANOL ((E)-3-methyl-5-(2,2,3- 1832 −2.5 trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol) CYCLOMYRAL (8,8-dimethyl- 1610 −2.4 1,2,3,4,5,6,7,8-octahydronaphthalene-2- carbaldehyde) FENCHYL ACETATE ((2S)-1,3,3- 1628 −2.2 trimethylbicyclo[2.2.1]heptan-2-yl acetate) SYLKOLIDE ((E)-2-((3,5-dimethylhex-3-en- 2177 −1.9 2-yl)oxy)-2-methylpropyl cyclopropanecarboxylate) BUTYL BUTYRO LACTATE (1-butoxy-1- 1680 −0.1 oxopropan-2-yl butyrate) DAMASCENONE GIV ((E)-1-(2,6,6- 1608 −1.5 trimethylcyclohexa-1,3-dien-1-yl)but-2-en-1- one) FRUITATE ((3aS,4S,7R,7aS)-ethyl 1617 −1.1 octahydro-1H-4,7-methanoindene-3a- carboxylate) IRONE ALPHA ((E)-4-(2,5,6,6- 1800 −1.5 tetramethylcyclohex-2-en-1-yl)but-3-en-2- one) CLONAL (dodecanenitrile) 1723 −1.0 DAMASCONE ALPHA ((E)-1-(2,6,6- 1657 −1.1 trimethylcyclohex-2-en-1-yl)but-2-en-1-one) DUPICAL ((E)-4-((3aS,7aS)-hexahydro-1H- 1607 −2.5 4,7-methanoinden-5(6H)-ylidene)butanal) VELOUTONE (2,2,5-trimethyl-5- 1778 −1.9 pentylcyclopentanone) SPIROGALBANONE (1-(spiro[4.5]dec-6- 1850 −2.0 en-7-yl)pent-4-en-1-one) ZINARINE (2-(2,4- 1557 −2.1 dimethylcyclohexyl)pyridine) BIGARYL (8-(sec-butyl)-5,6,7,8- 1563 −2.0 tetrahydroquinoline) CASSYRANE (5-tert-butyl-2-methyl-5- 1624 −1.6 propyl-2H-furan) CITRATHAL R ((Z)-1,1-diethoxy-3,7- 1933 −1.1 dimethylocta-2,6-diene) ROSYFOLIA ((1-methyl-2-(5-methylhex-4- 1685 −1.0 en-2-yl)cyclopropyl)-methanol) (3-(4-isobutyl-2-methylphenyl)propanal) 1700 −2.5

Encapsulated perfume compositions containing GROUP 2 perfume ingredients in the amounts referred to herein above are resistant to leakage when suspended in harshly extractive media, such as solid and liquid laundry care detergents.

Those encapsulated perfume compositions described hereinabove containing perfume ingredients characterized by a RECON_VOLTAE value larger than about 1540 Bohr³, wherein those ingredients are additionally characterized by having a log₁₀ Kcaps greater than −3 (i.e. GROUP 2 ingredients) form additional embodiments of the present invention.

Furthermore, solid or liquid laundry detergent compositions, and particular those formats designed as unit dosage forms contained in pouches or pods, and often referred to in the art as “liquid tabs”, containing said encapsulated perfume compositions form further embodiments of the present invention.

A GROUP 3 of perfume ingredients is characterized by ingredients having RECON_VOLTAE values larger than 1750 Bohr³ and log₁₀ Kcaps greater than −3. Perfume ingredients of GROUP 3 include but are not limited to:

RECON_VOLTAE Perfumery ingredient (Bohr3) LogKcaps ADOXAL (2,6,10-trimethylundec-9-enal) 1878 −2.5 AMBER CORE (1-((2-(tert- 1972 −2.3 butyl)cyclohexyl)oxy)butan-2-ol) AMBERMAX (1,3,4,5,6,7-hexahydro- 2275 −2.8 .beta.,1,1,5,5-pentamethyl-2H-2,4a- Methanonaphthalene-8-ethanol) AMBROCENIDE ((4aR,5R,7aS,9R)- 2339 −2.1 Octahydro-2,2,5,8,8,9a-hexamethyl-4H-4a,9- methanoazuleno[5,6-d]-1,3-dioxole) BELAMBRE ((1R,2S,4R)-2′-isopropyl-1,7,7- 2112 −1.6 trimethylspiro[bicyclo[2.2.1]heptane-2,4′- [1,3]dioxane]) BOISAMBRENE FORTE 2063 −2.0 ((ethoxymethoxy)cyclododecane) BOISIRIS ((1S,2R,5R)-2-ethoxy-2,6,6- 1914 −1.0 trimethyl-9-methylenebicyclo[3.3.1]nonane) CARYOPHYLLENE ((Z)-4,11,11-trimethyl- 1809 −1.0 8-methylenebicyclo[7.2.0]undec-4-ene) CASHMERAN (1,1,2,3,3-pentamethyl- 1772 −1.9 2,3,6,7-tetrahydro-1H-inden-4(5H)-one) CITRONELLYL PROPIONATE (3,7- 1808 −2.0 dimethyloct-6-en-1-yl propionate) COSMONE ((Z)-3-methylcyclotetradec-5- 1924 −2.5 enone) DIMETHYL BENZYL CARBINYL 1767 −1.6 BUTYRATE (2-methyl-1-phenylpropan-2-yl butyrate) EBANOL ((E)-3-methyl-5-(2,2,3- 1832 −2.5 trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol) ETHYL LINALYL ACETATE ((Z)-3,7- 1783 −1.1 dimethylnona-1,6-dien-3-yl acetate) FIXOLIDE (1-(3,5,5,6,8,8-hexamethyl- 2207 −2.2 5,6,7,8-tetrahydronaphthalen-2-yl)ethanone) GERANYL ISOBUTYRATE ((E)-3,7- 1901 −1.2 dimethylocta-2,6-dien-1-yl isobutyrate) GIVESCONE (ethyl 2-ethyl-6,6- 1754 −1.5 dimethylcyclohex-2-enecarboxylate) HABANOLIDE ((E)-oxacyclohexadec-12- 1978 −2.6 en-2-one) HEDIONE (methyl 3-oxo-2- 1784 −2.4 pentylcyclopentaneacetate) HEXYL CINNAMIC ALDEHYDE ((E)-2- 1778 −2.5 benzylideneoctanal) IRONE ALPHA ((E)-4-(2,5,6,6- 1800 −1.5 tetramethylcyclohex-2-en-1-yl)but-3-en-2- one) ISO E SUPER (1-(2,3,8,8-tetramethyl- 2024 −1.4 1,2,3,4,5,6,7,8-octahydronaphthalen-2- yl)ethanone) ISORALDEINE 70 ((E)-3-methyl-4-(2,6,6- 1806 −2.0 trimethylcyclohex-2-en-1-yl)but-3-en-2-one) KARANAL (5-(sec-butyl)-2-(2,4- 2242 −1.4 dimethylcyclohex-3-en-1-yl)-5-methyl-1,3- dioxane) METHYL CEDRYL KETONE (1-((1S,8aS)- 2076 −1.9 1,4,4,6-tetramethyl-2,3,3a,4,5,8-hexahydro- 1H-5,8a-methanoazulen-7-yl)ethanone) NECTARYL (2-(2-(4-methylcyclohex-3-en- 1822 −1.9 1-yl)propyl)cyclopentanone) NEROLIDYLE ((Z)-3,7,11-trimethyldodeca- 2257 −2.3 1,6,10-trien-3-yl acetate) PARADISAMIDE (2-ethyl-N-methyl-N-(m- 1790 −3.0 tolyl)butanamide) PETALIA (2-cyclohexylidene-2-(o- 1753 −1.4 tolyl)acetonitrile) PRECYCLEMONE B (1-methyl-4-(4- 1783 −2.2 methylpent-3-en-1-yl)cyclohex-3- enecarbaldehyde) RADJANOL SUPER ((E)-2-ethyl-4-(2,2,3- 1829 −2.3 trimethylcyclopent-3-en-1-yl)but-2-en-1-ol) SERENOLIDE (2-(1-(3,3- 2429 −2.0 dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate) SYLKOLIDE ((E)-2-((3,5-dimethylhex-3-en- 2177 −1.9 2-yl)oxy)-2-methylpropyl cyclopropanecarboxylate) THIBETOLIDE (oxacyclohexadecan-2-one) 2017 −2.2 TRIDECENE-2-NITRILE ((E)-tridec-2- 1818 −2.2 enenitrile) VELOUTONE (2,2,5-trimethyl-5- 1778 −1.9 pentylcyclopentanone) SPIROGALBANONE (1-(spiro[4.5]dec-6- 1850 −2.0 en-7-yl)pent-4-en-1-one) CITRATHAL R ((Z)-1,1-diethoxy-3,7- 1933 −1.1 dimethylocta-2,6-diene)

Encapsulated perfume compositions containing perfume ingredients of GROUP 3 in amounts referred to hereinabove, are resistant to leakage when suspended in harshly extractive media, such as encountered in shampoos and personal care cleansing compositions.

Those encapsulated perfume compositions described hereinabove containing perfume ingredients characterized by a RECON_VOLTAE value larger than about 1200 Bohr³, wherein those ingredients are additionally characterized by having a log₁₀ Kcaps greater than −3 (i.e. GROUP 3 ingredients) form additional embodiments of the present invention.

Furthermore, personal care cleansing compositions, including shampoos and hair conditioners, containing said encapsulated perfume compositions form still further embodiments of the present invention.

A particular challenge that faces formulators of encapsulated perfume compositions is how to strike an acceptable balance between microcapsule stability (i.e. the resistance to leakage of perfume ingredients from microcapsules dispersed in a suspending medium) and performance, (that is, the ability of a microcapsule to deliver a perfume impression once deposited on a substrate). Typically, if microcapsules are particularly stable during storage in extractive bases, then they tend to be rather robust and will only release perfume, if at all, upon application of high shear forces. When such microcapsules are deposited on substrates, such as fabric, hair or skin, a perfume impression may only be noticeable with vigorous rubbing of the treated substrate. Such microcapsules are said to possess “post-rub” performance, but often their pre-rub odour impression is weak or non-existent.

The provision of stable microcapsules, and particularly microcapsules that are stable in aggressive or extractive media, that exhibit acceptable pre-rub odour impression remains challenging.

The present invention articulates another physicochemical parameter that correlates well with performance, and particularly the pre-rub odour impression of perfume ingredients encapsulated in core shell microcapsules.

The intrinsic Pre-Rub Odour Contribution (“PROC”) of a perfume ingredient is given by the concentration (wt %) of a perfume ingredient to be encapsulated, multiplied by its standard Odour Value (OV_(i)), and by its equilibrium headspace-capsule partition coefficient Kcaps. Hence for each perfume ingredient i, a Pre-Rub Odour Contribution is defined by

PROC_(i)=OV_(i)[log₁₀ Kcaps_(i)+3]

Furthermore, the partial Pre-Rub Odour Contribution (pPROC) of an ingredient is defined as its concentration (wt %) in the perfume multiplied by its standard Odour Value (OV_(i)) and by its equilibrium headspace-capsule partition coefficient Kcaps. Hence for each perfume ingredient i, a partial Pre-Rub Odour Contribution is defined by

pPROC_(i) =c _(i)OV_(i)[log₁₀ Kcaps+3]

Finally, the total Pre-Rub Odour Contribution (tPROC) is the sum of the partial Pre-Rub Odour Contribution (pPROC) over all ingredients in an encapsulated perfume composition.

The standard Odour Value (OV_(i)) is defined as the ratio of the standard equilibrium headspace concentration of the ingredient to the Odour Detection Threshold of this ingredient.

The term “standard equilibrium headspace concentration” used hereinabove refers to the concentration of a perfume ingredient in equilibrium with its condensed form (that is, its solid or liquid form) at a temperature of 25° C. and under a pressure of 1 atmosphere. It can be measured by using any of the quantitative headspace analysis techniques known in the art, see for example Mueller and Lamparsky in Perfumes: Art, Science and Technology, Chapter 6 “The Measurement of Odors” at pages 176-179 (Elsevier 1991).

The term Odour Detection Threshold (ODT₁) used herein refers to the average concentration above which a perfume ingredient i can be perceived by a panellist and can be measured by olfactometry, as described, for example in Mueller and Lamparsky (op. cit).

The equilibrium headspace concentration may be measured as follows: 500 mg of the test compound is added to a headspace container which is then sealed. The container is then incubated at constant 25° C. until the compound reached equilibrium between the gas and the liquid phase. A defined volume of this saturated headspace (usually 0.5-110 is trapped on a micro filter using a styrene/divinyl benzene porous material, such as Porapak™ Q (available from Sigma -Aldrich) as sorbent. After filter extraction with an appropriate solvent (usually 30-100 ul methyl tert. butyl ether), an aliquot of the extract is analyzed by gas chromatography (GC). Quantification is performed by the external standard calibration method. The concentration in the original headspace can be calculated (in terms of μg/l) from the headspace volume sucked through the micro filter and the aliquot of the filter extract injected into the gas chromatograph. The final headspace concentration value of a given test compound is obtained as the mean value of three independent measurements. Further information of the technique hereinabove described may be found in the article of Etzweiler, F.; Senn E. and Neuner-Jehle N., Ber. Bunsen-Ges. Phys. Chem. 1984, 88, 578-583, which is hereby incorporated by reference.

The Odour Detection Threshold (ODT_(i)) may be measured by using an olfactometer. The following steps can be carried out and the odor thresholds for each compounds listed in Table 1 determined.

The olfactometer functions on the principle of a linear dilution of an odorant in a carrier gas. The quantity of odorant displaced depends on its vapor pressure and the carrier gas flow. A constant flow of nitrogen, regulated by a flow regulator, carries the odorant from a sample container to a mixing chamber. There, the carrier gas-odor mixture is diluted with odourless air. From the mixing chamber one part of the diluted odorous air is allowed to flow via a fused silica capillary to the sniffing funnel. The flow rate through the capillary, which determines the dosage of odorous air from the mixing chamber into the sniffing funnel, depends on the opening the valve which can be regulated via PC from 1 to 256 ml in binary steps. The final dilution of the odorous air sample occurs in the glass funnel by flushing them permanently with odourless air at a flow rate of 8 lt/min. Forced-choice triangle presentation is achieved by a special automated channel setting device where only one position of a switch the odorant delivering capillary enters in the sniffing funnel, whereas in two other positions the capillary is positioned outside the funnel and where the effluent is sucked away. After each trial the channel setting is changed automatically and in a random order. The concentration is calculated from the odorants vapour pressure and from the dilution ratios that were applied in the olfactometer, assuming that vapour pressure saturation is achieved in the sample generator. As a control the concentration is determined analytically by sampling a known volume from the capillary effluent into a headspace filter and by subsequent gas chromatographic quantitation of the odourant in the desorption solution.

Each panellist (panel of 15 persons) starts sniffing at the olfactometer at a concentration level at which he perceives the odorant at medium intensity. After three correct answers in three consecutive trials (or four correct answers of five trials) at the same level, stimulus concentration is decreased by a factor of two to the next lower level, and so on, until the panellist has reached his threshold level. The final threshold value of a given odorant is obtained as the mean value of all individual threshold levels.

Encapsulated perfume compositions of the present invention displaying good pre-rub performance may be prepared by selecting perfume ingredients on the basis of their PROC values, such that the total Pre-Rub Odour Contribution of the perfume ingredients encapsulated in the composition is be between about 0.5×10⁸ and 1.0×10⁹, more particularly between 1×10⁸ and 8×10⁸ and more particularly still between 1.5×10⁸ and 6×10⁸.

Still further, in order to obtain encapsulated perfume compositions comprising core-shell microcapsules having optimal performance in terms of stability with respect to leakage, particularly in highly extractive/aggressive media and performance, in particular pre-rub performance, the perfume ingredients may be selected on the basis of their PROC values, such that the total Pre-Rub Odour Contribution of the perfume ingredients encapsulated in the composition should be between about 0.5×10⁸ and 1×10⁹, more particularly between 1×10⁸ and 8×10⁸ and more particularly still between 1.5×10⁸ and 6×10⁸, and the distribution of perfume ingredient RECON_VOLTAE and log₁₀ Kcaps values are within the ranges as disclosed hereinabove.

A GROUP 4 of perfume ingredients, and their respective PROC values is listed in the Table below. It is preferred that encapsulated perfume compositions having high total PROC values are composed of the GROUP 4 ingredients specified herein below, although having regard to the teaching of the present invention, the skilled person may easily calculate the PROC values of other perfume ingredients not listed, and use them in encapsulated perfume compositions of the present invention.

GROUP 4 perfumery ingredients include but are not limited to:

Perfumery ingredient PROC MANZANATE (ethyl 2-methylpentanoate) 99577526 DAMASCONE DELTA ((E)-1-(2,6,6-trimethylcyclohex-3-en-1-yl)but-2-en- 65924274 1-one) DAMASCENONE ((E)-1-(2,6,6-trimethylcyclohexa-1,3-dien-1-yl)but-2-en- 33149935 1-one) EUCALYPTOL ((1s,4s)-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octane) 20085069 ETHYL CAPROATE (ethyl hexanoate) 16063000 NONENAL-6-CIS ((Z)-non-6-enal) 14610000 ALDEHYDE C 12 MNA (2-methylundecanal) 6849504 GALBANONE PURE (1-(3,3-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one) 4793532 BIGARYL (8-(sec-butyl)-5,6,7,8-tetrahydroquinoline) 4223123 MELONAL (2,6-dimethylhept-5-enal) 3633579 DAMASCONE ALPHA ((E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en- 1869529 1-one) ROSYRANE SUPER (4-methylene-2-phenyltetrahydro-2H-pyran) 1841920 PELARGENE (2-methyl-4-methylene-6-phenyltetrahydro-2H-pyran) 1768363 SPIROGALBANONE (1-(spiro[4.5]dec-6-en-7-yl)pent-4-en-1-one) 1489842 ETHYL SAFRANATE (ethyl 2,6,6-trimethylcyclohexa-1,3-diene-1- 1446690 carboxylate) DECENAL-4-TRANS ((E)-dec-4-enal) 1068978 CASSYRANE (5-tert-butyl-2-methyl-5-propyl-2H-furan) 911423 DELPHONE (2-pentylcyclopentanone) 771798 TERPINOLENE (1-methyl-4-(propan-2-ylidene)cyclohex-1-ene) 672048 IONONE BETA ((E)-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-3-en-2-one) 668147 ETHYL OENANTHATE (ethyl heptanoate) 467433 ALLYL AMYL GLYCOLATE (allyl 2-(isopentyloxy)acetate) 448677 LINALOOL (3,7-dimethylocta-1,6-dien-3-ol) 405669 ISOCYCLOCITRAL (2,4,6-trimethylcyclohex-3-enecarbaldehyde) 362665 ISOPROPYL METHYL-2-BUTYRATE (isopropyl 2-methyl butanoate) 320608 FLORHYDRAL (3-(3-isopropylphenyl)butanal) 294597 DIMETOL (2,6-dimethylheptan-2-ol) 294170 ROSYFOLIA (3-(4-isobutyl-2-methylphenyl)propanal) 279858 3-(4-isobutyl-2-methylphenyl)propanal (3-(4-isobutyl-2- 279536 methylphenyl)propanal) METHYL OCTYNE CARBONATE (methyl non-2-ynoate) 270258 JASMACYCLENE ((3aR,6S,7aS)-3a,4,5,6,7,7a-hexahydro-1H-4,7- 259747 methanoinden-6-yl acetate) CYCLOGALBANATE (allyl 2-(cyclohexyloxy)acetate) 220660 FLOROPAL (2,4,6-trimethyl-4-phenyl-1,3-dioxane) 215929 DIPENTENE (1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene) 189713 FRUITATE ((3aS,4S,7R,7aS)-ethyl octahydro-1H-4,7-methanoindene-3a- 176891 carboxylate) METHYL PAMPLEMOUSSE (6,6-dimethoxy-2,5,5-trimethylhex-2-ene) 151438 IRISONE PURE ((E)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one) 143717 IRISONE ALPHA ((E)-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one) 143714 LIFFAROME ((Z)-hex-3-en-1-yl methyl carbonate) 141869 CASHMERAN (1,1,2,3,3-pentamethyl-2,3,6,7-tetrahydro-1H-inden-4(5H)- 141286 one) TETRAHYDRO LINALOOL (3,7-dimethyloctan-3-ol) 140812 CITRONELLAL (3,7-dimethyloct-6-enal) 126286 ETHYL LINALOOL ((E)-3,7-dimethylnona-1,6-dien-3-ol) 122602 LEMONILE ((2E,6Z)-3,7-dimethylnona-2,6-dienenitrile) 112447 RHUBAFURAN (2,4-dimethyl-4-phenyltetrahydrofuran) 109862 FLOROCYCLENE ((3aR,6S,7aS)-3a,4,5,6,7,7a-hexahydro-1H-4,7- 109419 methanoinden-6-yl propionate) EBANOL ((E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2- 106853 ol) HEXENYL-3-CIS BUTYRATE ((Z)-hex-3-en-1-yl butyrate) 97634 ISORALDEINE 70 ((E)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but- 83954 3-en-2-one) MENTHONE (2-isopropyl-5-methylcyclohexanone) 83516 ETHYL CAPRYLATE (ethyl octanoate) 81140 GIVESCONE (ethyl 2-ethyl-6,6-dimethylcyclohex-2-enecarboxylate) 76022 CITRONELLYL NITRILE (3,7-dimethyloct-6-enenitrile) 71124 JASMONE CIS ((Z)-3-methyl-2-(pent-2-en-1-yl)cyclopent-2-enone) 66032 FENCHYL ALCOHOL ((1S,2R,4R)-1,3,3-trimethylbicyclo[2.2.1]heptan-2- 65384 ol) RADJANOL SUPER ((E)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but- 64782 2-en-1-ol) UNDECAVERTOL ((E)-4-methyldec-3-en-5-ol) 61799 DUPICAL ((E)-4-((3aS,7aS)-hexahydro-1H-4,7-methanoinden-5(6H)- 60602 ylidene)butanal) BOISAMBRENE FORTE ((ethoxymethoxy)cyclododecane) 59050 ALDEHYDE C 11 MOA (2-methyldecanal) 58883 ISO E SUPER (1-(2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2- 52929 yl)ethanone) DIMETHYL OCTENONE (4,7-dimethyloct-6-en-3-one) 51879 TERPINENE GAMMA (1-methyl-4-propan-2-ylcyclohexa-1,4-diene) 51728 FRESKOMENTHE (2-(sec-butyl)cyclohexanone) 49849 HEDIONE (methyl 3-oxo-2-pentylcyclopentaneacetate) 47438 CLONAL (dodecanenitrile) 46090 GARDOCYCLENE ((3aR,6S,7aS)-3a,4,5,6,7,7a-hexahydro-1H-4,7- 42816 methanoinden-6-yl isobutyrate) HERBANATE ((2S)-ethyl 3-isopropylbicyclo[2.2.1]hept-5-ene-2- 38513 carboxylate) LILIAL (3-(4-(tert-butyl)phenyl)-2-methylpropanal) 32603 SYLKOLIDE ((E)-2-((3,5-dimethylhex-3-en-2-yl)oxy)-2-methylpropyl 32277 cyclopropanecarboxylate) GERANIOL ((E)-3,7-dimethylocta-2,6-dien-1-ol) 32071 KOAVONE ((Z)-3,4,5,6,6-pentamethylhept-3-en-2-one) 31805 ROSACETOL (2,2,2-trichloro-1-phenylethyl acetate) 31559 CYCLAMEN ALDEHYDE (3-(4-isopropylphenyl)-2-methylpropanal) 31268 ALLYL CYCLOHEXYL PROPIONATE (allyl 3-cyclohexylpropanoate) 29587 BELAMBRE 50%/IPM ((1R,2S,4R)-2′-isopropyl-1,7,7- 27187 trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane]) NONADYL (6,8-dimethylnonan-2-ol) 26158 FRUTONILE (2-methyldecanenitrile) 24822 TRIDECENE-2-NITRILE ((E)-tridec-2-enenitrile) 24181 PYRALONE (6-(sec-butyl)quinoline) 23864 STEMONE ((E)-5-methylheptan-3-one oxime) 22947 CITRAL LEMAROME N ((E)-3,7-dimethylocta-2,6-dienal) 20039 METHYL CEDRYL KETONE (1-((1S,8aS)-1,4,4,6-tetramethyl-2,3,3a,4,5,8- 19783 hexahydro-1H-5,8a-methanoazulen-7-yl)ethanone) ALDEHYDE C 110 UNDECYLIC (undecanal) 18200 SILVIAL (3-(4-isobutylphenyl)-2-methylpropanal) 16666 ALDEHYDE C 11 UNDECYLENIC (undec-10-enal) 15988 CITRONELLOL (3,7-dimethyloct-6-en-1-ol) 15832 ROSALVA (dec-9-en-1-ol) 14982 VELOUTONE (2,2,5-trimethyl-5-pentylcyclopentanone) 14571 MYRALDENE (4-(4-methylpent-3-en-1-yl)cyclohex-3-enecarbaldehyde) 13927 AMYL SALICYLATE (pentyl 2-hydroxybenzoate) 13880 TETRAHYDRO MYRCENOL (2,6-dimethyloctan-2-ol) 13764 BOISIRIS ((1S,2R,5R)-2-ethoxy-2,6,6-trimethyl-9- 13558 methylenebicyclo[3.3.1]nonane) NECTARYL (2-(2-(4-methylcyclohex-3-en-1-yl)propyl)cyclopentanone) 13091 METHYL NONYL KETONE EXTRA (undecan-2-one) 11831 PETALIA (2-cyclohexylidene-2-(o-tolyl)acetonitrile) 10949 FLORALOZONE (3-(4-ethylphenyl)-2,2-dimethylpropanal) 10053 PEONILE (2-cyclohexylidene-2-phenylacetonitrile) 9995 AGRUMEX (2-(tert-butyl)cyclohexyl acetate) 9864 IRONE ALPHA ((E)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2- 9686 one) ORIVONE (4-(tert-pentyl)cyclohexanone) 9146 NEOBERGAMATE FORTE (2-methyl-6-methyleneoct-7-en-2-yl acetate) 8351 ISONONYL ACETATE (3,5,5-trimethylhexyl acetate) 7732 ALLYL OENANTHATE (allyl heptanoate) 7580 DIMETHYL BENZYL CARBINYL ACETATE (2-methyl-1-phenylpropan- 7061 2-yl acetate) COSMONE ((Z)-3-methylcyclotetradec-5-enone) 6460 SERENOLIDE (2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl 5947 cyclopropanecarboxylate) RASPBERRY KETONE (N112) (4-(4-hydroxyphenyl)butan-2-one) 5860 ETHYL LINALYL ACETATE ((Z)-3,7-dimethylnona-1,6-dien-3-yl acetate) 5526 DIMETHYL BENZYL CARBINYL BUTYRATE (2-methyl-1- 5269 phenylpropan-2-yl butyrate) MALTYL ISOBUTYRATE (2-methyl-4-oxo-4H-pyran-3-yl isobutyrate) 5209 HEXYL SALICYLATE (hexyl 2-hydroxybenzoate) 4862 AMBER CORE (1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol) 4356 PRECYCLEMONE B (1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3- 4350 enecarbaldehyde) HEXYL ISOBUTYRATE (hexyl isobutyrate) 4190 ADOXAL (2,6,10-trimethylundec-9-enal) 3827 THIBETOLIDE (oxacyclohexadecan-2-one) 3525 NEOFOLIONE ((E)-methyl non-2-enoate) 3459 TERPINYL ACETATE (2-(4-methylcyclohex-3-en-1-yl)propan-2-yl acetate) 3429 FENCHYL ACETATE ((2S)-1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl 3166 acetate) SUPER MUGUET ((E)-6-ethyl-3-methyloct-6-en-1-ol) 2813 KARANAL (5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3- 2751 dioxane) CITRONELLYL PROPIONATE (3,7-dimethyloct-6-en-1-yl propionate) 2710 LINALYL ACETATE SYNTHETIC (3,7-dimethylocta-1,6-dien-3-yl acetate) 2676 BUTYL CYCLOHEXYL ACETATE PARA (4-(tert-butyl)cyclohexyl 2526 acetate) CYCLOHEXYL SALICYLATE (cyclohexyl 2-hydroxybenzoate) 2454 ALDEHYDE C 12 LAURIC (dodecanal) 2369 APHERMATE (1-(3,3-dimethylcyclohexyl)ethyl formate) 2320 GERANYL ISOBUTYRATE ((E)-3,7-dimethylocta-2,6-dien-1-yl 1972 isobutyrate) CITRONELLYL ACETATE (3,7-dimethyloct-6-en-1-yl acetate) 1744 ALDEHYDE MANDARINE ((E)-dodec-2-enal) 1675 BORNYL ACETATE ((2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl 1498 acetate) VIRIDINE ((2,2-dimethoxyethyl)benzene) 1437 CITRONELLYL FORMATE (3,7-dimethyloct-6-en-1-yl formate) 1414 PIVAROSE (2,2-dimethyl-2-pheylethyl propanoate) 1206 MENTHOL NATURAL (2-isopropyl-5-methylcyclohexanol) 1177 AMBERMAX (1,3,4,5,6,7-hexahydro-.beta.,1,1,5,5-pentamethyl-2H-2,4a- 1066 Methanonaphthalene-8-ethanol) BUTYL BUTYRO LACTATE (1-butoxy-1-oxopropan-2-yl butyrate) 999 CITRATHAL R ((Z)-1,1-diethoxy-3,7-dimethylocta-2,6-diene) 995 HABANOLIDE ((E)-oxacyclohexadec-12-en-2-one) 991 INDOFLOR (4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine) 830 CORANOL (4-cyclohexyl-2-methylbutan-2-ol) 740 CARYOPHYLLENE ((Z)-4,11,11-trimethyl-8- 609 methylenebicyclo[7.2.0]undec-4-ene) GERANYL ACETATE ((E)-3,7-dimethylocta-2,6-dien-1-yl acetate) 593 PARADISAMIDE (2-ethyl-N-methyl-N-(m-tolyl)butanamide) 550 FIXOLIDE (1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2- 550 yl)ethanone) NERYL ACETATE HC ((Z)-3,7-dimethylocta-2,6-dien-1-yl acetate) 472 DIMETHYL BENZYL CARBINOL (2-methyl-1-phenylpropan-2-ol) 264 HEXYL CINNAMIC ALDEHYDE ((E)-2-benzylideneoctanal) 192 NEROLIDYLE ((Z)-3,7,11-trimethyldodeca-1,6,10-trien-3-yl acetate) 175

Error! Not a valid link.Error! Not a valid link.It is preferred that an encapsulated perfume composition of the present invention contains at least 3, more particularly at least 5, still more particularly at least 7, and more particularly still, at least 9 GROUP 4 perfume ingredients.

Those encapsulated perfume compositions described hereinabove additionally comprising GROUP 4 ingredients, and in particular at least 3, more particularly at least 5, still more particularly at least 7, and more particularly still, at least 9 GROUP 4 perfume ingredients represent additional aspects of the present invention.

Furthermore, fabric softener or conditioning compositions, particularly those containing structured surfactants; or solid or liquid laundry detergent compositions, and particularly those formats designed as unit dosage forms contained in pouches or pods, and often referred to in the art as “liquid tabs”; or harshly extractive media, including personal care cleansing compositions, such as shampoos, containing encapsulated perfume compositions described herein comprising GROUP 4 ingredients, form further embodiments of the present invention.

In a particular embodiment of the present invention, an encapsulated perfume composition is characterized in that the total Pre-Rub Odour Contribution of the encapsulated perfume ingredients is between 0.5×10⁸ and 1.0×10⁹, more particularly between 1×10⁸ and 8×10⁸ and more particularly still, between 1.5×10⁸ and 6×10⁸; and the distribution of RECON_VOLTAE values of encapsulated perfume ingredients is such that

-   -   70 wt % or more, more particularly 80 wt % or more, and more         particularly still 90 wt % or more of the perfume ingredients         have known RECON_VOLTAE values larger than 1200 Bohr³; and     -   0.1 to 30 wt %, more particularly from 1 to 20 wt % and more         particularly still, from 1 to 10 wt % of perfume ingredients         having RECON_VOLTAE values below 1200 Bohr³.

In another particular aspect of the present invention, an encapsulated perfume composition is characterized in that the total Pre-Rub Odour Contribution of the encapsulated perfume ingredients is between 0.5×10⁸ and 1.0×10⁹, more particularly between 1×10⁸ and 8×10⁸ and more particularly still between 1.5×10⁶ and 6×10⁶; and the distribution of known RECON_VOLTAE values of encapsulated perfume ingredients is such that

-   -   30 wt % or more, more particularly 35 wt % or more, and more         particularly still 40 wt % or more of the perfume ingredients         have known RECON_VOLTAE values larger than 1540 Bohr³; and     -   20 to 60 wt %, more particularly 25 to 50 wt %, and more         particularly still 30 to 40 wt % of the perfume ingredients have         known RECON_VOLTAE values from 1200 Bohr³ to 1540 Bohr³; and     -   0.1 to 30 wt %, more particularly from 1 to 20 wt % and more         particularly still from 1 to 10 wt % of perfume ingredients have         known RECON_VOLTAE values below 1200 Bohr³.

In another particular embodiment of the present invention, an encapsulated perfume composition contains encapsulated perfume ingredients characterized by a total Pre-Rub Odour Contribution between 0.5×10⁸ and 1.0×10⁹, more particularly 1×10⁸ and 8×10⁸ and more particularly still 1.5×10⁸ and 6×10⁸; and the distribution of known RECON_VOLTAE values of encapsulated perfume ingredients is such that:

-   -   0.5 to 30, more particularly from 1 to 25 wt % and more         particularly still from 5 to 20 wt % of at least one perfume         ingredient have known RECON_VOLTAE values above 1750 Bohr³; and     -   20 to 60 wt % or more, more particularly 25 to 55 wt % or more,         and more particularly still 30 to 50 wt % or more of the perfume         ingredients have known RECON_VOLTAE values from 1540 Bohr³ to         1750 Bohr³; and     -   5 to 50 wt % or more, particularly 10 to 40 wt % or more, and         more particularly still 15 to 30 wt % or more of the perfume         ingredients have known RECON_VOLTAE values from 1200 Bohr³ to         1540 Bohr³ ; and     -   0.1 to 30 wt %, more particularly from 1 to 20 wt % and more         particularly still from 1 to 10 wt % of perfume ingredients have         known RECON_VOLTAE values below 1200 Bohr³.

In another particular embodiment of the present invention, an encapsulated perfume composition contains encapsulated perfume ingredients characterized by a total Pre-Rub Odour Contribution between 0.5×10⁸ and 1.0×10⁹, more particularly between 1×10⁸ and 8×10⁸ and more particularly still between 1.5×10⁸ and 6×10⁸; and the distribution of known RECON_VOLTAE values of encapsulated perfume ingredients is such that:

-   -   70 wt % or more, more particularly 80 wt % or more, and more         particularly still 90 wt % or more of the perfume ingredients         have known RECON_VOLTAE values larger than 1750 Bohr³; and     -   0.1 to 30 wt %, more particularly from 1 to 20 wt % and more         particularly still from 1 to 10 wt % of the perfume ingredients         have RECON_VOLTAE values below 1750 Bohr³.

Other perfume ingredients that may be employed in the present invention and their respective RECON VOLTAE and log_(in) Kcaps values are set forth in the following table. One of more of the following perfume ingredients may be contained in encapsulated perfume compositions according to the present invention.

Ingredient (NAME (IUPAC name)) RECON_VOLTAE Log Kcaps ACETAL CD ((2-benzyl-1,3-dioxolan-4-yl)methanol) 1387 −4.0 ACETAL E ((2-(1-ethoxyethoxy)ethyl)benzene) 1531 −1.1 ACETAL R ((2-(1-propoxyethoxy)ethyl)benzene) 1661 −1.2 ACETANISOLE (1-(4-methoxyphenyl)ethanone) 1114 −2.3 ACETATE PA (allyl 2-phenoxyacetate) 1407 −3.5 ACETOIN (3-hydroxybutan-2-one) 690 −1.4 ACETOPHENONE (acetophenone) 923 −1.5 ACETYL CARYOPHYLLENE ((Z)-4,11,11-trimethyl-8- 2092 −1.0 methylenebicyclo[7.2.0]undec-4-ene) ACETYL ISOEUGENOL CRYSTALS ((E)-2-methoxy-4-(prop-1-en- 1526 −2.8 1-yl)phenyl acetate) AGARBOIS (N-ethyl-N-(m-tolyl)propionamide) 1537 −3.0 ALCOHOL C 10 DECYLIC (decan-1-ol) 1432 −2.7 ALCOHOL C 12 LAURIC (dodecan-1-ol) 1690 −2.5 ALCOHOL C 13 OXO (tridecan-1-ol) 1819 −2.4 ALCOHOL C 6 HEXYLIC (hexan-1-ol) 915 −2.9 ALCOHOL C 8 OCTYLIC (octan-1-ol) 1173 −3.0 ALCOHOL C 9 NONYLIC (nonan-1-ol) 1302 −3.0 ALDEHYDE C 6 HEXYLIC FOOD GRADE (hexan-1-ol) 885 −2.8 ALDEHYDE C 7 HEPTYLIC (heptanal) 1016 −2.7 ALDEHYDE C 8 OCTYLIC FOOD GRADE (octanal) 1145 −2.7 ALDEHYDE C 9 ISONONYLIC (3,5,5-trimethylhexanal) 1317 −2.5 ALDEHYDE C 9 NONYLIC FOOD GRADE (nonanal) 1274 −2.8 ALICATE (2,6-dimethylheptan-4-yl acetate) 1605 −1.8 ALLYL CAPROATE (allyl hexanoate) 1307 −1.8 AMBERKETAL (3,8,8,11a-tetramethyldodecahydro-1H-3,5a- 2339 −4.0 epoxynaphtho[2,1-c]oxepine) AMBRETTOLIDE ((Z)-oxacycloheptadec-10-en-2-one) 2108 −5.0 AMBRINOL (2,5,5-trimethyl-1,2,3,4,4a,5,6,7- 1651 −2.3 octahydronaphthalen-2-ol) AMBROCENIDE ((4aR,5R,7aS,9R)-Octahydro-2,2,5,8,8,9a- 2339 −2.1 hexamethyl-4H-4a,9-methanoazuleno[5,6-d]-1,3-dioxole) AMBROFIX (3a,6,6,9a-tetramethyldodecahydronaphtho[2,1- 2039 −2.0 b]furan) AMBROXAN (3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b- 2039 −2.0 octahydro-1H-benzo[e][1]benzofuran) AMYL ACETATE (pentyl acetate) 1075 −1.2 AMYL BENZOATE (pentyl benzoate) 1494 −1.2 AMYL BUTYRATE (pentyl butanoate) 1333 −1.6 AMYL CINNAMIC ALDEHYDE ((Z)-2-benzylideneheptanal) 1649 −2.8 AMYL PHENYL ACETATE (pentyl 2-phenylacetate) 1623 −2.9 AMYL VINYL CARBINOL (oct-1-en-3-ol) 1149 −2.9 ANAPEAR ((E)-methyl octa-4,7-dienoate) 1257 −2.8 ANATOLYL (phenethyl 2-methylbutanoate) 1625 −2.1 ANETHOLE ((E)-1-methoxy-4-(prop-1-en-1-yl)benzene) 1175 −1.7 ANISYL ACETATE (4-methoxybenzyl acetate) 1309 −3.6 ANISYL ALCOHOL ((4-methoxyphenyl)methanol) 1021 −4.0 ANTHER ((2-(isopentyloxy)ethyl)benzene) 1597 −1.3 AUBEPINE PARA CRESOL (4-methoxybenzaldehyde) 981 −2.1 AZARBRE (3,5-diethyl-2,5-dimethylcyclohex-2-enone) 1591 −1.5 BENZALDEHYDE (benzaldehyde) 790 −0.9 BENZOPHENONE (benzophenone) 1347 −1.5 BENZYL ACETATE (benzyl acetate) 1118 −1.6 BENZYL ACETONE (4-phenylbutan-2-one) 1180 −1.8 BENZYL ALCOHOL (phenylmethanol) 831 −2.6 BENZYL BENZOATE (benzyl benzoate) 1539 −3.6 BENZYL BUTYRATE (benzyl butanoate) 1378 −1.7 BENZYL CINNAMATE (benzyl 3-phenylprop-2-enoate) 1748 −2.5 BENZYL FORMATE (benzyl formate) 984 −2.0 BENZYL ISOBUTYRATE (benzyl isobutanoate) 1374 −1.4 BENZYL ISOVALERATE (benzyl 3-methylbutanoate) 1510 −1.4 BENZYL METHYL ETHER ((methoxymethyl)benzene) 960 −2.2 BENZYL PHENYL ACETATE (benzyl 2-phenylacetate) 1669 −5.2 BENZYL PROPIONATE (benzyl propionate) 1249 −1.6 BENZYL SALICYLATE (benzyl 2-hydroxybenzoate) 1601 −5.0 BICYCLO NONALACTONE (octahydro-2H-chromen-2-one) 1160 −2.6 BIGARADE OXIDE ((4aS,6R,7S,8aR)-3,3,6,7-tetramethyl- 1610 −1.2 2,4,4a,5,6,7,8,8a-octahydrochromene) BISABOLENE ((E)-1-methyl-4-(6-methylhepta-2,5-dien-2- 1804 −0.8 yl)cyclohex-1-ene) BORNEOL CRYSTALS ((1S,2S,4S)-1,7,7- 1345 −2.0 trimethylbicyclo[2.2.1]heptan-2-ol) BOURGEONAL (3-(4-(tert-butyl)phenyl)propanal) 1609 −3.2 BUCCOXIME ((1R,5S,E)-1,5-dimethylbicyclo[3.2.1]octan-8-one 1402 −2.3 oxime) BUTYL ISOBUTYRATE, ISO-(2-methylpropyl 2- 1202 −1.7 methylpropanoate) BUTYL QUINOLINE SECONDARY (6-(sec-butyl)quinoline) 1466 −1.8 CALMODE (1,2,4-trimethoxy-5-propylbenzene) 1602 −3.3 CALONE 1951 (7-methyl-2H-benzo[b][1,4]dioxepin-3(4H)-one) 1228 −0.9 CALYPSONE (6-methoxy-2,6-dimethyloctanal) 1596 −2.5 CAMPHENE ((1S,4R)-2,2-dimethyl-3- 1202 −0.3 methylenebicyclo[2.2.1]heptane) CAMPHOR ((1S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one) 1301 −1.9 CANTHOXAL (3-(4-methoxyphenyl)-2-methylpropanal) 1372 −3.3 CARAMEL LACTONE (3-hydroxy-4,5-dimethylfuran-2(5H)-one) 885 −3.5 CARVACROL (5-isopropyl-2-methylphenol) 1217 −2.0 CARVONE LAEVO (2-methyl-5-(prop-1-en-2-yl)cyclohex-2- 1249 −1.2 enone) CASSIONE (4-(1-3-benzodioxol-5-yl)-2-butanone) 1360 −2.8 CELERY KETONE (3-methyl-5-propylcyclohex-2-enone) 1262 −1.4 CENTIFOLYL (2-phenylethyl 2,2-dimethylpropanoate) 1665 −2.0 CEPIONATE (methyl 2-(3-oxo-2-pentylcyclopentyl)acetate) 1784 −2.4 CETALOX (3a,6,6,9a-tetramethyl-2,4,5,5a,7,8,9,9b-octahydro- 2039 −2.1 1H-benzo[e][1]benzofuran) CETONAL (2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1- 1825 −2.6 yl)butanal) CETONE ALPHA ((E)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en- 1782 −1.6 1-yl)but-3-en-2-one) CETONE V ((E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6- 2028 −3.3 dien-3-one) CINNAMALVA ((E)-3-phenylprop-2-en-1-yl acetate) 1075 −2.0 CINNAMIC ALCOHOL ((E)-3-phenylprop-2-en-1-ol) 1048 −2.4 CINNAMIC ALDEHYDE ((2E)-3-phenylprop-2-enal) 1001 −2.0 CINNAMYL ACETATE ((E)-3-phenylprop-2-en-1-yl acetate) 1334 −1.7 CINNAMYL CINNAMATE (3-phenylprop-2-enyl 3-phenylprop- 1967 −3.2 2-enoate) CITRAL DIMETHYL ACETAL ((E)-1,1-dimethoxy-3,7- 1680 −1.9 dimethylocta-2,6-diene) CITRONELLYL ISOBUTYRATE (3,7-dimethyloct-6-en-1-yl 1936 −1.3 isobutanoate) CITRONELLYL OXYACETALDEHYDE (2-((3,7-dimethyloct-6-en-1- 1679 −3.4 yl)oxy)acetaldehyde) CIVETTONE ((Z)-cycloheptadec-9-enone) 2180 −2.5 CLARITONE (2,4,4,7-tetramethyloct-6-en-3-one) 1658 −0.9 CONIFERAN (2-(tert-pentyl)cyclohexyl acetate) 1807 −1.9 CORPS CASSIS (2-(2-mercaptopropan-2-yl)-5- 1483 −2.2 methylcyclohexanone) CORPS PAMPLEMOUSSE PURE ((4S)-4,7,7-trimethyl-6- 1374 0.1 thiabicyclo[3.2.1]octane) CORYLONE DRIED (2-hydroxy-3-methylcyclopent-2-enone) 822 −2.8 COUMARIN (2H-chromen-2-one) 985 −1.9 CREOSOL (2-methoxy-4-methylphenol) 1021 −2.6 CRESOL PARA (p-cresol) 830 −1.8 CRESYL ACETATE PARA (p-tolyl acetate) 1115 −2.2 CRESYL CAPRYLATE PARA (p-tolyl octanoate) 1892 −2.6 CRESYL ISOBUTYRATE PARA (p-tolyl isobutanoate) 1374 −1.9 CRESYL METHYL ETHER PARA (1-methoxy-4-methylbenzene) 959 −1.8 CRESYL PHENYL ACETATE PARA (p-tolyl 2-phenylacetate) 1666 −4.9 CUMIN NITRILE (4-isopropylbenzonitrile) 1246 −1.2 CUMINIC ALDEHYDE (4-isopropylbenzaldehyde) 1177 −1.0 CUMINYL ALCOHOL ((4-isopropylphenyl)methanol) 1217 −2.8 CYCLAL C (2,4-dimethylcyclohex-3-enecarbaldehyde) 1138 −1.9 CYCLEMONE A (8,8-dimethyl-1,2,3,4,5,6,7,8- 1610 −2.4 octahydronaphthalene-2-carbaldehyde) CYCLOHEXAL (4-(4-hydroxy-4-methylpentyl)cyclohex-3- 1719 −3.7 enecarbaldehyde) CYCLOHEXYL ETHYL ACETATE (2-cyclohexylethyl acetate) 1371 −1.9 CYCLOMETHYLENE CITRONELLOL (3-(4-methylcyclohex-3-en- 1425 −1.9 1-yl)butan-1-ol) CYDRANE (hexyl 2-methylbutanoate) 1588 −0.5 CYMENE PARA (1-methyl-4-propan-2-ylbenzene) 1155 −0.6 CYPRISATE (methyl 1,4-dimethylcyclohexanecarboxylate) 2826 −2.0 DAMASCONE BETA ((E)-1-(2,6,6-trimethylcyclohex-1-en-1- 1655 −1.3 yl)but-2-en-1-one) DECADIENAL ((2E,4E)-deca-2,4-dienal) 1309 −2.2 DECALACTONE DELTA (6-pentyltetrahydro-2H-pyran-2-one) 1378 −3.2 DECALACTONE GAMMA (5-hexyloxolan-2-one) 1386 −3.7 DECANONITRILE (decanenitrile) 1464 −1.5 DECATONE (6-isopropyloctahydronaphthalen-2(1H)-one) 1610 −2.2 DECEN-1-AL, CIS-4-((Z)-dec-4-enal) 1363 −2.8 DECENAL-2-TRANS ((E)-dec-2-enal) 1356 −2.1 DECENAL-9 (9-decenal) 1369 −3.3 DELTA-3 CARENE ((1S,6S)-3,7,7-trimethylbicyclo[4.1.0]hept-3- 1200 −1.0 ene) DIETHYL MALONATE (diethyl propanedioate) 1152 −1.4 DIHEXYL FUMARATE (dihexyl-but-2-enedioate) 2263 −1.7 DIHYDRO AMBRATE (2-(sec-butyl)-1-vinylcyclohexyl acetate) 1865 −2.4 DIHYDRO EUGENOL (2-methoxy-4-propylphenol) 1281 −2.5 DIHYDRO FARNESAL ((Z)-3,7,11-trimethyldodeca-6,10-dienal) 1967 −4.0 DIHYDRO IONONE BETA (4-(2,6,6-trimethylcyclohex-1-en-1- 1695 −1.5 yl)butan-2-one) DIHYDRO LINALOOL (3,7-dimethyloct-6-en-3-ol) 1403 −2.0 DIHYDRO MYRCENOL (2,6-dimethyloct-7-en-2-ol) 1410 −2.8 DIHYDRO MYRCENYL ACETATE (2,6-dimethyloct-7-en-2-yl 1695 −2.3 acetate) DIHYDRO TERPINEOL (2-(4-methylcyclohexyl)propan-2-ol) 1356 −2.0 DIHYDRO TERPINYL ACETATE (2-(4-methylcyclohexyl)propan- 1639 −1.5 2-yl acetate) DIMETHYL ANTHRANILATE (methyl 2-(methylamino)benzoate) 1206 −3.0 DIMETHYL HYDROQUINONE CRYSTALS (1,4- 1022 −2.9 dimethoxybenzene) DIMETHYL PHENYL ETHYL CARBINOL (2-methyl-4- 1352 −2.2 phenylbutan-2-ol) DIMYRCETOL (2,6-dimethyloct-7-en-2-ol) 2969 −1.9 DIPHENYL METHANE (diphenylmethane) 1320 −1.4 DIPHENYL OXIDE (oxydibenzene) 1260 −1.2 DISPIRONE (7,9-dimethylspiro[5.5]undecan-3-one) 1648 −2.4 DODECALACTONE DELTA (6-heptyltetrahydro-2H-pyran-2- 1636 −3.4 one) DODECALACTONE GAMMA (5-octyloxolan-2-one) 1644 −3.9 ESTRAGOLE (1-allyl-4-methoxybenzene) 1180 −1.7 ETHYL 2,4-DECADIENOATE ((2E,4Z)-ethyl deca-2,4-dienoate) 1625 −1.5 ETHYL ACETATE (ethyl acetate) 685 −0.7 ETHYL ACETO ACETATE (ethyl 3-oxobutanoate) 964 −1.0 ETHYL AMYL KETONE (octan-3-one) 1146 −1.3 ETHYL BENZOATE (ethyl benzoate) 1106 −1.7 ETHYL BUTYRATE (ethyl butanoate) 945 −1.2 ETHYL CINNAMATE (ethyl 3-phenylprop-2-enoate) 1317 −1.0 ETHYL ISOAMYL KETONE (6-methylheptan-3-one) 1149 −1.2 ETHYL ISOBUTYRATE (ethyl 2-methylpropionate) 940 −0.8 ETHYL ISOVALERATE (ethyl 3-methylbutanoate) 1077 −1.3 ETHYL LAITONE (8-ethyl-1-oxaspiro[4.5]decan-2-one) 1429 −2.2 ETHYL MALTOL (2-ethyl-3-hydroxy-4H-pyran-4-one) 985 −3.7 ETHYL METHYL-2-BUTYRATE (ethyl 2-methylbutanoate) 1069 −0.6 ETHYL PELARGONATE (ethyl nonanoate) 1591 −2.4 ETHYL PHENYL ACETATE (ethyl 2-phenylacetate) 1236 −2.6 ETHYL PHENYL GLYCIDATE (ethyl 3-phenyloxirane-2- 1347 −1.9 carboxylate) ETHYL PROPIONATE (ethyl propionate) 816 −2.0 ETHYL SALICYLATE (ethyl 2-hydroxybenzoate) 1168 −1.2 ETHYL VANILLIN (3-ethoxy-4-hydroxybenzaldehyde) 1168 −2.2 ETHYL-2 DIMETHYL-3,5 PYRAZINE (2-ethyl-3,5- 1100 −2.4 dimethylpyrazine) ETHYLENE BRASSYLATE (1,4-dioxacycloheptadecane-5,17- 2096 −3.0 dione) EUGENOL PURE (4-allyl-2-methoxyphenol) 1242 −2.8 EUGENYL ACETATE (4-allyl-2-methoxyphenyl acetate) 1527 −3.5 EVERNYL (methyl 2,4-dihydroxy-3,6-dimethylbenzoate) 1362 −3.6 FARNESENE ((E)-7,11-dimethyl-3-methylenedodeca-1,6,10- 1863 −2.2 triene) FARNESOL ((2E,6Z)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol) 1962 −4.5 FENCHONE ALPHA (1,3,3-trimethylbicyclo[2.2.1]heptan-2- 1301 −1.6 one) FENNALDEHYDE (3-(4-methoxyphenyl)-2-methylpropanal) 1372 −3.3 FLEURANIL (3-(4-ethylphenyl)-2,2-dimethylpropanenitrile) 1674 −1.7 FLORALYM (2,6-dimethyloct-7-en-2-ol) 1410 −2.8 FLORAMAT (2-(tert-butyl)cyclohexyl ethyl carbonate) 1863 −0.5 FLORIDILE ((E)-undec-9-enenitrile) 1560 −2.8 FLOROL (2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol) 1432 −2.5 FLOROSA (tetrahydro-4-methyl-2-(2-methylpropyl)-2H-pyran- 1432 −2.5 4-ol) FLORYMOSS ((Z)-1-(cyclooct-3-en-1-yl)propan-1-ol) 1451 −2.9 FOLENOX (4,4,8,8-tetramethyloctahydro-4a,7- 1865 −1.5 methanonaphtho[1,8a-b]oxirene) FOLIONE (methyl oct-2-ynoate) 1246 −1.7 FOLROSIA (4-isopropylcyclohexanol) 1229 −2.3 FRAISTONE (ethyl 2-(2,4-dimethyl-1,3-dioxolan-2-yl)acetate) 1440 −3.1 FRESCILE (3-methyldodecanenitrile) 1859 −1.9 FRUCTONE (ethyl 2-(2-methyl-1,3-dioxolan-2-yl)acetate) 1307 −3.3 GALAXOLIDE (4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 2160 −4.3 hexahydrocyclopenta[g]isochromene) GARDAMIDE (N,2-dimethyl-N-phenylbutanamide) 1534 −2.5 GARDENOL (1-phenylethyl acetate) 1246 −1.7 GEORGYWOOD (1-(1,2,8,8-tetramethyl-1,2,3,4,5,6,7,8- 2037 −1.3 octahydronaphthalen-2-yl)ethanone) GERANODYLE (2-(2-hydroxypropan-2-yl)-5- 1420 −4.0 methylcyclohexanol) GERANYL ACETONE ((E)-6,10-dimethylundeca-5,9-dien-2-one) 1705 −1.1 GERANYL CROTONATE ((E)-3,7-dimethylocta-2,6-dien-1-yl but- 1862 −2.3 2-enoate) GERANYL FORMATE ((E)-3,7-dimethylocta-2,6-dien-1-yl 1510 −1.6 formate) GERANYL PHENYL ACETATE ((E)-3,7-dimethylocta-2,6-dien-1- 2194 −3.8 yl 2-phenylacetate) GERANYL PROPIONATE ((E)-3,7-dimethylocta-2,6-dien-1-yl 1773 −1.6 propionate) GLYCOLIERRAL (2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en- 1854 −1.6 2-yl)-1,3-dioxolane) GRISALVA (3a-ethyl-6,6,9a- 2203 −2.6 trimethyldodecahydronaphtho[1,2-c]furan) GRISAMBROL B (ethyl picolinate) 1076 −2.4 GUAIACOL (2-methoxyphenol) 893 −2.9 GUAIYL ACETATE (2-(3,8-dimethyl-1,2,3,4,5,6,7,8- 2161 −1.9 octahydroazulen-5-yl)propan-2-yl acetate) GYRANE (2-butyl-4,6-dimethyl-3,6-dihydro-2H-pyran) 1446 −2.1 HELIOTROPINE (benzo[d][1,3]dioxole-5-carbaldehyde) 971 −1.4 HELVETOLIDE (2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2- 2388 −3.1 methylpropyl propionate) HEPTALACTONE GAMMA (5-propyloxolan-2-one) 996 −2.2 HERBAVERT (3-ethoxy-1,1,5-trimethylcyclohexane) 1520 −1.4 HERBOXANE (2-butyl-4,4,6-trimethyl-1,3-dioxane) 1562 −3.7 HERCOLYN D (methyl 7-isopropyl-1,4a-dimethyl- 2656 −5.0 1,2,3,4,4a,4b,5,6,7,8,10,10a-dodecahydrophenanthrene-1- carboxylate) HEXENAL-2-TRANS (E-hex-2-enal) 841 −1.7 HEXENOL-2-TRANS ((E)-hex-2-en-1-ol) 886 −2.5 HEXENOL-3-CIS ((Z)-hex-3-en-1-ol) 876 −2.5 HEXENYL ACETATE CIS (cis-hex-3-enyl acetate) 1165 −1.4 HEXENYL HEXENOATE CIS-3 ((Z)-(Z)-hex-3-en-1-yl hex-3- 1644 −3.4 enoate) HEXENYL-3-CIS ACETATE ((Z)-hex-3-en-1-yl acetate) 1162 −1.4 HEXENYL-3-CIS BENZOATE ((Z)-hex-3-en-1-yl benzoate) 1584 −2.4 HEXENYL-3-CIS FORMATE ((Z)-hex-3-en-1-yl formate) 1029 −1.9 HEXENYL-3-CIS ISOBUTYRATE ((Z)-hex-3-en-1-yl isobutanoate) 1420 −0.7 HEXENYL-3-CIS METHYL-2-BUTYRATE ((Z)-hept-3-en-1-yl 2- 1549 −1.5 methyl butanoate) HEXENYL-3-CIS PROPIONATE ((Z)-hex-3-en-1-yl propionate) 1292 −1.2 HEXENYL-3-CIS SALICYLATE ((Z)-hex-3-en-1-yl 2- 1646 −3.5 hydroxybenzoate) HEXENYL-3-CIS TIGLATE ((E)-(Z)-hex-3-en-1-yl 2-methylbut-2- 1505 −1.8 enoate) HEXENYL-3-TRANS ACETATE ((E)-hex-3-enyl] acetate) 1162 −1.5 HEXYL ACETATE (hexyl acetate) 1202 −1.2 HEXYL BENZOATE (hexyl benzoate) 1623 −1.4 HEXYL BUTYRATE (hexyl butanoate) 1462 −1.8 HEXYL PROPIONATE (hexyl propionate) 1333 −1.5 HOMOFURONOL (2-ethyl-4-hydroxy-5-methylfuran-3(2H)- 1025 −3.6 one) HYDRATROPIC ALDEHYDE (2-phenylpropanal) 1048 −2.4 HYDROXYCITRONELLAL DIMETHYL ACETAL (8,8-dimethoxy- 1831 −3.0 2,6-dimethyloctan-2-ol) HYDROXYCITRONELLAL (7-hydroxy-3,7-dimethyloctanal) 1472 −4.2 IRISANTHEME ((E)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en- 1806 −1.7 1-yl)but-3-en-2-one) IRIVAL ((E)-non-2-enenitrile) 1301 −1.4 ISO CYCLO GERANIOL ((2,4,6-trimethylcyclohex-3-en-1- 1295 −1.6 yl)methanol) ISOAMYL ACETATE (isopentyl acetate) 1075 −1.2 ISOAMYL BUTYRATE (isopentyl butanoate) 1335 −0.5 ISOAMYL PROPIONATE (isopentyl propionate) 1206 −1.1 ISOBUTYL BENZOATE (2-methylpropyl benzoate) 1368 −1.4 ISOBUTYL ISOBUTYRATE (2-methylpropyl 2- 1202 −1.7 methylpropanoate) ISOBUTYL METHOXY PYRAZINE (2-methylpropyl 3- 1311 −2.2 methoxypyrazine) ISOBUTYL PHENYLACETATE (2-methylpropyl 2-phenylacetate) 1497 −2.0 ISOBUTYL QUINOLINE-2 (6-butan-2-yl-quinoline) 1473 −1.6 ISOBUTYL SALICYLATE (isobutyl 2-hydroxybenzoate) 1430 −1.6 ISOEUGENOL ((E)-2-methoxy-4-(prop-1-en-1-yl)phenol) 1238 −2.5 ISOJASMONE T (2-hexylcyclopent-2-enone) 1411 −2.0 ISOLONGIFOLANONE (2,2,7,7- 1900 −1.5 tetramethyltricyclo[6.2.1.01,6]undecan-5-one) ISOMENTHONE DL (2-isopropyl-5-methylcyclohexanone) 1315 −1.5 ISONONANOL (3,5,5-trimethylhexan-1-ol) 1345 −2.4 ISOPENTYRATE (4-methylpent-4-en-2-yl isobutanoate) 1434 −1.2 ISOPROPYL QUINOLINE (6-isopropylquinoline) 1336 −1.7 ISOPULEGOL (5-methyl-2-(prop-1-en-2-yl)cyclohexanol) 1315 −2.3 ISORALDEINE CETONE ALPHA ((E)-3-methyl-4-(2,6,6- 1806 −1.6 trimethylcyclohex-2-en-1-yl)but-3-en-2-one) JASMAL (3-pentyltetrahydro-2H-pyran-4-yl acetate) 1709 −4.3 JASMATONE (2-hexylcyclopentanone) 1439 −2.2 JASMIN LACTONE DELTA ((Z)-6-(pent-2-en-1-yl)tetrahydro-2H- 1343 −2.4 pyran-2-one) JASMIN LACTONE GAMMA ((Z)-5-(hex-3-en-1-yl)-5- 1472 −2.4 methyloxolan-2-one) JASMOLACTONE ((E)-6-(pent-3-en-1-yl)tetrahydro-2H-pyran- 1341 −2.5 2-one) JASMONYL (3-butyl-5-methyltetrahydro-2H-pyran-4-yl 1708 −3.1 acetate) JASMOPYRANE (3-pentyltetrahydro-2H-pyran-4-yl acetate) 1709 −3.0 JAVANOL ((1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3- 1930 −3.0 yl)methyl)cyclopropyl)methanol) KEFARENE (1-(4-methoxy-2,2,6,6-tetramethylcyclohex-3-en-1- 1807 −2.0 yl)ethanone) KEPHALIS (4-(1-ethoxyvinyl)-3,3,5,5- 1936 −2.4 tetramethylcyclohexanone) KOHINOOL (3,4,5,6,6-pentamethylheptan-2-ol) 1751 −2.1 LABIENONE ((E)-2,4,4,7-tetramethylnona-6,8-dien-3-one) 1748 −1.4 LABIENOXIME ((3E,6E)-2,4,4,7-tetramethylnona-6,8-dien-3- 1850 −4.0 one oxime) LACTOSCATONE (2,8,8-trimethyloctahydro-1H-4a,2- 1804 −2.6 (epoxymethano)naphthalen-10-one) LAITONE (8-isopropyl-1-oxaspiro[4.5]decan-2-one) 1561 −2.2 LIMETOL (2,2,6-trimethyl-6-vinyltetrahydro-2H-pyran) 1332 −1.3 LINALOOL OXIDE (2-(5-methyl-5-vinyltetrahydrofuran-2- 1395 −2.5 yl)propan-2-ol) LINALYL CINNAMATE (3,7-dimethylocta-1,6-dien-3-yl 3- 2286 −2.2 phenylprop-2-enoate) LINALYL FORMATE (3,7-dimethylocta-1,6-dien-3-yl formate) 1520 −2.0 LINALYL ISOBUTYRATE (3,7-dimethylocta-1,6-dien-3-yl 1911 −1.4 isobutanoate) LINALYL PROPIONATE (3,7-dimethylocta-1,6-dien-3-yl 1783 −1.9 propionate) LINDENOL (2-(4-methylcyclohex-3-en-1-yl)propan-2-ol) 1307 −1.7 LONGIFOLENE STD ((3R,3aR,8R,8aS)-4,4,8-trimethyl-9- 1799 −1.0 methylenedecahydro-3,8-methanoazulene) MACEAL (bicyclo[2.2.2]oct-5-ene-2-carboxaldehyde) 1573 −3.0 MAGNOLAN (2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2- 1509 −3.0 d][1,3]dioxine) MAHONIAL ((4E)-9-hydroxy-5,9-dimethyl-4-decenal) 1685 −3.5 MAJANTOL (2,2-dimethyl-3-(m-tolyl)propan-1-ol) 1507 −2.4 MALTOL (3-hydroxy-2-methyl-4H-pyran-4-one) 854 −3.9 MARENIL (2-(4-(tert-butyl)phenyl)acetonitrile) 1542 −2.1 MAYOL ((4-isopropylcyclohexyl)methanol) 1345 −2.7 MEFRANAL (3-methyl-5-phenylpentanal) 1443 −2.7 MEFROSOL (3-methyl-5-phenylpentan-1-ol) 1471 −3.5 MELOZONE (tricyclo[5.2.1.02,6]decane-3-carbaldehyde) 1260 −1.9 MENTHANYL ACETATE (2-(4-methylcyclohexyl)propan-2-yl 1639 −1.5 acetate) METAMBRATE (2-(sec-butyl)-1-methylcyclohexyl acetate) 1772 −1.7 METHOXY MELONAL (6-methoxy-2,6-dimethylheptanal) 1468 −2.5 METHOXY PHENYL BUTANONE (4-(4-methoxyphenyl)butan-2- 1372 −2.6 one) METHYL ACETOPHENONE (1-(p-tolyl)ethanone) 1051 −1.4 METHYL AMYL KETONE (heptan-2-one) 1015 −1.0 METHYL ANTHRANILATE (methyl 2-aminobenzoate) 1077 −4.0 METHYL BENZOATE (methyl benzoate) 981 −2.3 METHYL CAMOMILLE (butyl 2-methylpentanoate) 1460 −0.2 METHYL CINNAMATE (methyl 3-phenylprop-2-enoate) 1192 −1.6 METHYL CINNAMIC ALDEHYDE ((Z)-2-methyl-3- 1132 −1.9 phenylacrylaldehyde) METHYL CRESOTATE PARA (methyl 2-hydroxy-5- 1172 −2.3 methylbenzoate) METHYL DECALACTONE GAMMA (5-hexyl-5-methyloxolan-2- 1517 −2.5 one) METHYL DIANTILIS (2-ethoxy-4-(methoxymethyl)phenol) 1338 −3.3 METHYL DIHYDRO ISOJASMONATE (methyl 3-oxo-2- 1784 −1.8 pentylcyclopentaneacetate) METHYL DIPHENYL ETHER (2-methoxy-1,1′-biphenyl) 1386 −1.9 METHYL EPI JASMONATE ((Z)-methyl 2-(3-oxo-2-(pent-2-en-1- 1742 −2.1 yl)cyclopentyl)acetate) METHYL GEOSMIN (4,4,8a-trimethyldecahydronaphthalen-4a- 1738 −2.8 ol) METHYL HEPTENONE PURE (6-methylhept-5-en-2-one) 1101 −0.6 METHYL HEXYL KETONE (octan-2-one) 1144 −1.2 METHYL ISO EUGENOL ((E)-1,2-dimethoxy-4-(prop-1-en-1- 1366 −3.0 yl)benzene) METHYL LAITONE (8-methyl-1-oxaspiro[4.5]decan-2-one) 1299 −2.0 METHYL LINOLEATE ((9E,12E)-methyl octadeca-9,12-dienoate) 2546 −2.9 METHYL METHYL BUTYRATE (methyl 2-methylbutanoate) 944 −2.2 METHYL PARA-CRESOL (1-methoxy-4-methylbenzene) 959 −2.0 METHYL PHENYL ACETATE (methyl 2-phenylacetate) 1111 −2.4 METHYL QUINOLINE PARA (6-methylquinoline) 1078 −1.8 METHYL SALICYLATE (methyl 2-hydroxybenzoate) 1043 −2.0 METHYL TUBERATE PURE (4-methyl-5-pentyldihydrofuran- 1385 −2.6 2(3H)-one) METHYL-2 BUTANOL-1 FR (2-methylbutan-1-ol) 789 −1.9 METHYL-2-PENTENOIC ACID, 2-((E)-2-methylpent-2-enoic 903 −1.6 acid) METHYL-3 METHOXY-3 BUTANOL (3-methoxy-3-methylbutan- 981 −3.0 1-ol) METHYLOCTYLACETALDEHYDE MOA (2-methyl-decanal) 1530 −2.6 MOXALONE (1a,3,3,4,6,6-hexamethyl-1a,2,3,4,5,6,7,7a- 1992 −2.8 octahydronaphtho[2,3-b]oxirene) MUSCENONE ((Z)-3-methylcyclopentadec-5-enone) 2053 −2.5 MUSCONE (3-methylcyclopentadecanone) 2095 −2.5 MUSK C14 (1,4-dioxacyclohexadecane-5,16-dione) 1967 −3.0 MUSK R1 (1,7-dioxacycloheptadecan-8-one) 2065 −2.9 MYRALDYL ACETATE ((4-(4-methylpent-3-en-1-yl)cyclohex-3- 1928 −1.6 en-1-yl)methyl acetate) MYRCENE 90 (7-methyl-3-methyleneocta-1,6-diene) 1259 −0.4 MYROXIDE (2,2-dimethyl-3-(3-methylpenta-2,4- 1282 −0.9 dienyl)oxirane) MYSTIKAL (2-methylundecanoic acid) 1722 −5.0 NEOCASPIRENE (10-isopropyl-2,7-dimethyl-1- 1715 −1.4 oxaspiro[4.5]deca-3,6-diene) NEROL C (3,7-dimethyl-2,6-octadien-1-ol) 1363 −2.1 NEROLEX ((Z)-3,7-dimethylocta-2,6-dien-1-ol) 1357 −2.2 NEROLIDOL ((E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol) 1971 −4.5 NEROLINE (2-ethoxynaphthalene) 1294 −1.1 NEROLIONE (1-(3-methylbenzofuran-2-yl)ethanone) 1251 −1.7 NIRVANOLIDE ((E)-13-methyloxacyclopentadec-10-en-2-one) 1981 −1.8 NONADIENAL ((2E,6Z)-nona-2,6-dienal) 1187 −1.9 NONADIENOL-2,6 ((2E,6Z)-nona-2,6-dien-1-ol) 1234 −2.5 NONADIENYL ACETATE ((2E,6Z)-nona-2,6-dien-1-yl acetate) 1520 −2.4 NONANYL ACETATE (nonanyl acetate) 1632 −1.7 NONENOL-6-CIS ((Z)-non-6-en-1-ol) 1263 −2.8 NOOTKATONE CRYSTALS (4,4a-dimethyl-6-(prop-1-en-2-yl)- 1848 −2.5 4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one) NOPYL ACETATE (2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2- 1669 −2.1 yl)ethyl acetate) OCIMENE ((E)-3,7-dimethylocta-1,3,6-triene) 1253 −0.7 OCTALACTONE DELTA (6-propyltetrahydro-2H-pyran-2-one) 1119 −2.8 OCTALACTONE GAMMA (5-butyloxolan-2-one) 1128 −3.4 OCTENOL (oct-1-en-3-ol) 1149 −2.9 OCTENYL ACETATE (oct-1-en-3-yl acetate) 1436 −1.8 OKOUMAL (2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8- 2422 −2.6 tetrahydronaphthalen-2-yl)-1,3-dioxolane) ONCIDAL ((E)-2,6,10-trimethylundeca-5,9-dienal) 1833 −2.8 OPALAL (7-isopropyl-8,8-dimethyl-6,10- 1831 −3.0 dioxaspiro[4.5]decane) ORANGER CRYSTALS (1-(2-naphtalenyl)-ethanone) 1262 −2.0 ORCINYL 3 (3-methoxy-5-methylphenol) 1021 −3.0 OSYROL (7-methoxy-3,7-dimethyloctan-2-ol) 1643 −3.2 OXANE (2-methyl-4-propyl-1,3-oxathiane) 1264 −1.8 OXYOCTALINE FORMATE (2,4a,5,8a-tetramethyl- 1974 −2.1 1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl formate) PANDANOL ((2-methoxyethyl)benzene) 1081 −1.9 PARMAVERT (1,1-dimethoxynon-2-yne) 1547 −1.9 PEACH PURE (5-heptyldihydrofuran-2(3H)-one) 1515 −3.9 PELARGOL (3,7-dimethyloctan-1-ol) 1438 −2.3 PEOMOSA (2-(o-tolyl)ethanol) 1078 −2.4 PEPPERWOOD (3,7-dimethylocta-1,6-dien-3-yl 1941 −2.6 dimethylcarbamate) PERANAT (2-methylpentyl 2-methylpentanoate) 1719 −0.9 PETIOLE ((2-isopropoxyethyl)benzene) 1347 −1.5 PHARAONE (2-cyclohexylhepta-1,6-dien-3-one) 1629 −2.3 PHENOXANOL (3-methyl-5-phenylpentan-1-ol) 1471 −2.5 PHENOXY ACETALDEHYDE (2-phenoxyacetaldehyde) 987 −2.9 PHENOXY ETHYL ALCOHOL (2-phenoxyethanol) 1007 −2.9 PHENOXY ETHYL ISOBUTYRATE (2-(phenoxy)ethyl 2- 1553 −4.3 methylpropionate) PHENYL ACETALDEHYDE (2-phenyl-ethanal) 919 −2.5 PHENYL ACETIC ACID PURE (2-phenylacetic acid) 981 −2.5 PHENYL ETHYL ACETATE (2-phenethyl acetate) 1237 −1.8 PHENYL ETHYL ALCOHOL (2-phenylethanol) 951 −2.4 PHENYL ETHYL CINNAMATE (2-phenethyl 3-phenylprop-2- 1870 −2.9 enoate) PHENYL ETHYL FORMATE (2-phenethyl formate) 1105 −2.1 PHENYL ETHYL ISOBUTYRATE (2-phenethyl isobutanoate) 1496 −2.7 PHENYL ETHYL ISOVALERATE (2-phenethyl 3- 1625 −2.2 methylbutanoate) PHENYL ETHYL PHENYLACETATE (2-phenethyl 2- 1788 −4.0 phenylacetate) PHENYL ETHYL SALICYLATE CRYSTALS (2-phenethyl 2- 1721 −5.0 hydroxybenzoate) PHENYL PROPIONIC ALDEHYDE (3-phenylpropanal) 1052 −2.6 PHENYL PROPYL ACETATE (3-phenylpropyl acetate) 1367 −1.7 PHENYL PROPYL ALCOHOL (3-phenylpropan-1-ol) 1081 −2.3 PINENE ALPHA (2,6,6-trimethylbicyclo[3.1.1]hept-2-ene) 1196 −0.7 PINENE BETA (6,6-dimethyl-2- 1204 −0.8 methylenebicyclo[3.1.1]heptane) PINO ACETALDEHYDE (3-(6,6-dimethylbicyclo[3.1.1]hept-2-en- 1483 −4.0 2-yl)propanal) PIVACYCLENE ((3aR,6S,7aS)-3a,4,5,6,7,7a-hexahydro-1H-4,7- 1851 −1.8 methanoinden-6-yl pivalate) PLICATONE ((4aS,8aR)-7-methyloctahydro-1,4- 1390 −1.7 methanonaphthalen-6(2H)-one) POIRENATE (ethyl 2-cyclohexylpropionate) 1499 −1.3 POMAROSE ((2E,5E)-5,6,7-trimethylocta-2,5-dien-4-one) 1443 −0.9 PRECARONE ((1S,4R,6S)-4,7,7-trimethyl-4-(3-methylbut-2-en- 1887 −3.3 1-yl)bicyclo[4.1.0]heptan-3-one) PRENYL ACETATE (3-methylbut-2-en-1-yl acetate) 1039 −2.2 PROPYL DIANTILIS (2-ethoxy-4-(isopropoxymethyl)phenol) 1606 −2.0 PRUNOLIDE (5-pentyldihydrofuran-2(3H)-one) 1257 −3.7 QUINTONE (2-pentylcyclopentanone) 1313 −1.9 RESEDAL (2-(cyclohexylmethyl)-4,4,6-trimethyl-1,3-dioxane) 1726 −1.4 RHUBOFIX ((2R,8aS)-3′,6-dimethyl-3,4,4a,5,8,8a-hexahydro- 1571 −1.2 1H-spiro[1,4-methanonaphthalene-2,2′-oxirane]) RHUBOFLOR ((4aR,8aS,E)-6-ethylideneoctahydro-2H-5,8- 1400 −1.7 methanochromene) ROSANTOLENE (1-(ethoxymethyl)-2-methoxybenzene) 1277 −2.2 ROSAPHEN (2-methyl-5-phenylpentan-1-ol) 1471 −2.5 ROSE OXIDE (4-methyl-2-(2-methylprop-1-en-1-yl)tetrahydro- 1320 −2.4 2H-pyran) ROSSITOL (3-isobutyl-1-methylcyclohexanol) 1489 −2.3 SAFRALEINE (2,3,3-trimethyl-2,3-dihydro-1H-inden-1-one) 1390 −1.8 SAFRANAL (2,6,6-trimethylcyclohexa-1,3-dienecarbaldehyde) 1263 −2.4 SANDELA CONCENTRATED (3-((1R,2S,4R,6R)-5,5,6- 1989 −2.8 trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexanol) SCENTENAL ((3aR,4R,6S,7R,7aR)-6-methoxyoctahydro-1H-4,7- 1453 −3.2 methanoindene-1-carbaldehyde) SCLARENE (4,5,6,7,8,9,10,11,12,13- 1680 −1.7 decahydrocyclododeca[d]oxazole) SHISOLIA (4-vinylcyclohex-1-enecarbaldehyde) 1103 −1.9 SKATOLE (3-methyl-1H-indole) 998 −3.9 SPIRAMBRENE (2′,2′,3,7,7- 2037 −2.9 pentamethylspiro[bicyclo[4.1.0]heptane-2,5′-[1,3]dioxane]) STRAWBERRY PURE (ethyl methyl phenyl glycidate) 1481 −2.0 STYRALLYL ACETATE (1-phenylethyl acetate) 1246 −2.0 STYRALLYL PROPIONATE (1-phenylethyl propionate) 1377 −1.6 SUPERFIX (1,1,3-trimethyl-3-phenyl-2,3-dihydro-1H-indene) 1959 −1.9 SYRINGA ALDEHYDE (2-(p-tolyl)acetaldehyde) 1046 −3.0 SYVERTAL (2-(heptan-3-yl)-1,3-dioxolane) 1428 −3.0 TANAISONE ((Z)-1-(cyclooct-3-en-1-yl)ethanone) 1275 −1.4 TANGERINOL ((E)-6,10-dimethylundeca-5,9-dien-2-yl acetate) 2033 −1.8 TERPINENE ALPHA (1-methyl-4-propan-2-ylcyclohexa-1,3- 1194 −0.5 diene) TERPINEOL PURE (2-(4-methylcyclohex-3-en-1-yl)propan-2-ol) 1307 −2.0 TETRAHYDRO CITRAL (3,7-dimethyloctanal) 1409 −2.4 TETRAHYDRO LINALYL ACETATE (3,7-dimethyloctan-3-yl 1733 −1.9 acetate) THIOGERANIOL ((E)-3,7-dimethylocta-2,6-diene-1-thiol) 1458 −1.1 THYMOL CRYSTALS (2-isopropyl-5-methylphenol) 1217 −1.8 TIMBEROL (1-(2,2,6-trimethylcyclohexyl)hexan-3-ol) 2040 −2.1 TOLYL ALDEHYDE PARA (4-methylbenzaldehyde) 918 −0.7 TOSCANOL (1-(cyclopropylmethyl)-4-methoxybenzene) 1261 −1.9 TRICYCLAL (2,4-dimethylcyclohex-3-enecarbaldehyde) 1138 −1.7 TRIDECENAL-2-TRANS ((E)-tridec-2-enal) 1744 −2.5 TRIFERNAL (3-phenylbutanal) 1178 −2.2 TRIMOFIX O (1-((2E,5Z,9Z)-2,7,8-trimethylcyclododeca-2,5,9- 2093 −3.0 trien-1-yl)ethanone) TROPIONAL (3-(benzo[d][1,3]dioxol-5-yl)-2-methylpropanal) 1361 −2.6 ULTRAVANIL (2-ethoxy-4-methylphenol) 1146 −2.3 UNDECALACTONE DELTA (6-hexyltetrahydro-2H-pyran-2-one) 1507 −3.3 UNDECATRIENE ((3E,5Z)-undeca-1,3,5-triene) 1379 −0.8 UNDECENE 2 NITRILE ((E)-undec-2-enenitrile) 1559 −1.5 VALEROLACTONE GAMMA (5-methyloxolan-2-one) 740 −2.3 VANILLIN (4-hydroxy-3-methoxybenzaldehyde) 1043 −3.1 VANITROPE ((E)-2-ethoxy-5-(prop-1-en-1-yl)phenol) 1363 −1.9 VELVIONE ((Z)-cyclohexadec-5-enone) 2050 −1.7 VERDALIA ((3aS,4R,6S,7R,7aR)-6-methoxy-3a,4,5,6,7,7a- 1267 −2.1 hexahydro-1H-4,7-methanoindene) VERDOL (2-(tert-butyl)cyclohexanol) 1395 −2.5 VERNALDEHYDE (1-methyl-4-(4-methylpentyl)cyclohex-3- 1826 −2.3 enecarbaldehyde) VERTOFIX COEUR (1-((1S,8aS)-1,4,4,6-tetramethyl- 2094 −1.9 2,3,3a,4,5,8-hexahydro-1H-5,8a-methanoazulen-7- yl)ethanone) VETIKOL ACETATE/CORPS RHUBARB (4-methyl-4- 1803 −2.4 phenylpentan-2-yl acetate) VETYNAL ((2R,5R,8S)-4,4,8- 2192 −3.7 trimethyltricyclo[6.3.1.02,5]dodecan-1-yl acetate) VIOLET NITRILE ((2E,6Z)-nona-2,6-dienenitrile) 1261 −1.6 VIOLIFF (undec-10-enenitrile) 1400 −1.5 YARA YARA (2-methoxynaphthalene) 1169 −1.8

The encapsulated perfume compositions of the present invention may be presented in the form of at least one microcapsule dispersed in a suitable suspending medium.

Many different types of microcapsule compositions have been proposed in the art for encapsulating perfume compositions. The microcapsules of the present invention may be prepared using a range of conventional methods and materials known to those skilled in the art.

For example, microcapsules can be formed by physico-chemical means, such as internal phase separation, layer-by-layer poly-electrolyte deposition, sol-gel processes or coacervation; or by chemical means such as interfacial polymerisation, in-situ polymerisation and polycondensation.

The process of coacervation typically involves encapsulation of a generally water-insoluble material by the precipitation of colloidal material(s) onto the surface of droplets of perfume composition. Coacervation may be simple e. g. using one colloid such as gelatine, or complex where two or possibly more colloids of opposite charge, such as gelatine and gum arabic or gelatine and carboxymethylcellulose, are used under carefully controlled conditions of pH, temperature and concentration. Coacervation techniques are described, e.g. in U.S. Pat. No. 2,800,458, U.S. Pat. No. 2,800,457, GB929403, EP385534 and EP376385, which are herein incorporated by reference.

In a process of interfacial polymerization, two reactants that react by polycondensation meet at an oil-water interface to produce shells from the reaction of at least one oil-soluble wall forming material present in an internal oil phase with at least one water-soluble wall forming material present in an aqueous external phase. A polymerisation reaction between the two wall-forming materials occurs resulting in the formation of covalent bonds at the interface of the oil and aqueous phases to form a microcapsule wall. Examples of microcapsules produced by this method are polyamide and polyurethane microcapsules.

Polycondensation involves forming a dispersion or emulsion of perfume droplets in an aqueous continuous phase containing a pre-condensate of polymeric materials under appropriate conditions of agitation to produce microcapsules of a desired size, and adjusting the reaction conditions to cause condensation of the pre-condensate by acid catalysis, resulting in the condensate separating from solution and surrounding the dispersed perfume droplets to produce a coherent film and the desired microcapsules. Polycondensation techniques are described, e. g. in U.S. Pat. No. 3,516,941, U.S. Pat. No. 4,520,142, U.S. Pat. No. 4,528,226, U.S. Pat. No. 4,681,806, U.S. Pat. No. 4,145,184 and GB2073132, which are herein incorporated by reference.

A preferred method for forming microcapsules useful herein is polycondensation, typically to produce aminoplast and poylurea microcapsules.

Aminoplast resins are the reaction products of one or more amines with one or more aldehydes, typically formaldehyde. Non-limiting examples of suitable amines include urea, thiourea, melamine and its derivates, benzoguanamine and acetoguanamine and combinations of amines. For example, good results have been obtained with aminoplast capsules of mixed resins of urea/formaldehyde and melamine/formaldehyde, stabilized with maleic anhydride copolymers, as well as with aminoplast terpolymers, comprising polyamines, polyols and methylene oxide moieties, stabilized with acrlymidosulfonates copolymers, as described in WO 2008/098387.

The aminoplast microcapsules described in WO 2008/098387, which is incorporated herein in its entirety, are preferred encapsulating media for the encapsulated perfume compositions of the present invention.

Alternatively, microcapsules can be obtained by oil-mediated radical polymerization—phase separation, as described in U.S. Pat. No. 6,951,836 B2, or by interfacial radical polymerization.

An encapsulated perfume composition of the present invention may be prepared and presented in the form of a slurry, in which the microcapsules are dispered in an aqueous suspending medium. If it is intended to present the encapsulated perfume composition in this form, the pH of the slurry may be adjusted to about 3 to 8 by the addition of a suitable acid, such as citric acid or formic acid and a preservative added.

Slurries of microcapsules will typically contain a suspending aid to ensure the microcapsules remain stably suspended and do not cream, form a sediment or otherwise agglomerate during storage. Suitable dispersing aids include pectin, alginate, arabinogalactan, carageenan, gellan gum, xanthan gum, guar gum, acrylates/acrylic polymers, water-swellable clays, fumed silicas, acrylate/aminoacrylate copolymers, and mixtures thereof. Preferred dispersants herein include those selected from the group consisting of acrylate/acrylic polymers, gellan gum, fumed silicas, acrylate/aminoacrylate copolymers, water-swellable clays, and mixtures thereof.

In order to prevent microbial contamination it is desirable that the microcapsule composition contains a preservative. The preservative may be contained in the core material and/or in the aqueous carrier. Suitable preservatives include quaternary compounds, biguanide compounds, and mixtures thereof.

In addition to any perfume composition that may be contained within the microcapsules, a slurry of microcapsules of the present invention may also contain free perfume in the suspending medium.

Alternatively, the encapsulated perfume composition, initially presented in the form of a slurry, may be dried to provide an encapsulated perfume composition in powder form. Drying may be carried out directly by spray drying or by fluid bed drying. Alternatively, the encapsulated perfume composition can be dried by decanting off the liquid from the slurry and drying the solids in an oven to produce a cake, which can then be rendered in powder form by a subsequent comminution step.

Whatever means are employed to dry the encapsulated perfume composition, in order to prevent aggregation and improve the bulk flow properties of the microcapsules, it may be desirable to add a flow aid to the slurry before or after the drying process. Suitable flow aids will be known to the skilled person in the art and will include, without limitation silica, starch, calcium carbonate and sodium sulphate.

The size of the microcapsules employed in encapsulated perfume compositions according to the present invention can be adjusted as desired for use in any particular application. Microcapsules can be prepared having a mean diameter of from about 0.001 to about 1,000 microns, preferably from about 1 to about 500 microns, more preferably from about 10 to about 100 microns, and even more preferably from about 10 to about 70 microns.

The mean particle size can be determined in a manner known in the art. A particular method of measuring particle size is light scattering. Light scattering measurements can be made using a Malvern Mastersizer.

Encapsulated perfume compositions according to the present invention may be incorporated into all manner of consumer products, including those used in household, laundry and personal care products, including cosmetic products. Such consumer products are well known in the art and reference may be made to the following works which are incorporated herein by reference:

Formulating Detergents and Personal Care Products A guide to Product Development by L Ho Tan Tai, ISBN 1-893997-10-3 published by the AOCS Press. Also to Volume 67 of the Surfactant Science Series Liquid Detergents ISBN 0-8247-9391-9 (Marcel Dekker Inc).

The encapsulated perfume compositions may be incorporated into consumer products at levels that provide the consumer product with about 0.03 wt % to 1 wt % of encapsulated perfume composition based on the weight of the consumer product. The amount of encapsulated perfume composition that should be added to a consumer product base in order to arrive at this level of fragrance will depend on a number of factors, including the amount of perfume ingredients loaded into microcapsules, and the form in which the encapsulated perfume composition is incorporated into the base. Typically, the encapsulated perfume composition is incorporated in the form of a slurry containing about 20 to 50 wt %, and more particularly 30 to 45 wt % of microcapsules, wherein the microcapsules contain only perfume ingredients and no other diluents or solvents. In such a case, in order to provide the consumer product with the levels of perfume described above, one would typically incorporate between about 0.1 wt % to about 3 wt % of slurry into a consumer product base.

In a particular embodiment of the present invention, the consumer product is a fabric treatment product, such as a fabric conditioner or softener.

Fabric softener and conditioner ingredients and formulations are disclosed in U.S. Pat. Nos. 6,335,315; 5,674,832; 5,759,990; 5,877,145; and 5,574,179, which are hereby incorporated by reference.

Fabric conditioners or softeners typically comprise nitrogen-containing cationic surfactants having one or two alkyl chain comprising 16 to 22 carbon atoms, and optionally hydroxyl groups. The cationic group is preferably a quartenary ammonium, imidazolium group, and amido amine acid salts. The quaternary ammonium group has additionally two to three alkyl groups having 1 to 4 carbon or hydroxyalkyl or hydroxyl groups, or alkoxy groups, having typically about 1 to about 10 ethylene oxide moieties, and an anion selected from the group of halides, hydroxides, acetates and methylsulfate. The long alkyl chain is preferably bound to the cationic group by a ester group. Typical examples of such fabric conditioning actives include esterquat (N-methyl-N,N,bis[2-(C16-C18-acetoxy)ethyl)]-N-(2-hydroxyethyl) ammonium methosulfate), diesterquat (N,N,N-trimethyl-N-[1,2-di-(C16-C18-acyloxy)propyl ammonium salts), DEEDMAC (N,N-dimethyl-N,N-bis([2-(-[(1-oxooctadecyl)oxy]ethyl) ammonium chloride, HEQ (N,N,N-trimethyl-N-[(Z)-2-hydroxy-3-[(1-oxo-octadec-9-enyl)oxy]] ammonium chloride, TEAQ (diquaternized methylsulfate salt of the reaction product between C10-C20 staturated and unsaturated fatty acids and triethanoloamine), glycerine-based polyol esterquats, ethyl-tallowalkyl imidazolinium methyl sulphate, ditallowalkyl dimethylammonium methyl sulfate, methyl tallowalkyl amido ethyl tallowalkyl imidazolinium methyl sulfate, b-hydroxyethyl ethylenediamine erivatives, polyammonium and the like, and mixture thereof.

Further fabric softening actives are disclosed, for example, in Ajad Farooq and Charles J. Schramm, Handbook of Detergents—Part E: Applications, Surfactant Science Series 141, p. 181-200, CRC-Press, Broken Sound Parway, 2009.

Typical non-ionic surfactants that may be present in fabric conditioners or softeners include, but are not limited to alkyl and alkylbenzyl alcohol alkoxylates or polyalkoxylated carboxylic acids, polyalkoxylated amines, polyalkoxylated glycol or glycerol esters, polyalkoxylated sorbitan esters or alkanoamides.

In another embodiment of the invention, the consumer product may be a laundry detergent composition.

Laundry detergent ingredients and formulations are disclosed in U.S. Pat. Nos. 5,929,022; 5,916,862; 5,731,278; 5,470,507; 5,466,802; 5,460,752; and 5,458,810, which are hereby incorporated by reference.

Powdered or liquid detergents typically comprise anionic, zwitterionic and/or non-ionic surfactants, and mixtures thereof.

Typical anionic surfactants include sodium lauryl sulfate, sodium laureth sulfate, sodium trideceth sulfate, ammonium lauryl sulfate, ammonium laureth sulfate, potassium laureth sulfate, linear alkyl benzene sulfonates, sodium tridecyl benzene sulfonate, sodium dodecyl benzene sulfonate, sodium xylene sulfonate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, lauryl sarcosine, cocoyl sarcosine, sodium lauryl sarcosinate, sodium lauroyl sarcosinate, triethylamine lauryl sulfate, triethylamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate, ammonium co-coyl sulfate, ammonium lauroyl sulfate, sodium cocoyl sulfate, sodium lauroyl sulfate, sodium cocoyl isethionate, potassium cocoyl sulfate, potassium lauryl sulfate, monoethanolamine cocoyl sulfate, monoethanolamine lauryl sulfate, triethanolamine lauryl sulfate, C5-C17 acyl-N-(C1-C4 alkyl) glucamine sulfate, C5-C17 acyl-N-(C1-C4 hydroxyalkyl) glucamine sulfate, sodium hydroxyethyl-2-decyl ether sulfates, sodium methyl-2-hydroxydecyl ether sulfates, sodium hydroxyethyl-2-dodecyl ether sulfates, sodium monoethoxylated lauryl alkyl sulfates, C12-C18 alkyl sulfonates, ethoxylated or native linear and ramified C12-C18 alcohol sulfates, ethoxylated or native linear and ramified C12-C18 alcohol sulfates, and mixtures thereof. Above anionic surfactants may also be used in their un-neutralized, acid form.

Typical non-ionic surfactants include C6-C24 alkyl ethoxylates with about 1-12 ethylene oxide units. The alkyl chain of the aliphatic alcohol can either be straight or branched, primary or secondary, and generally contains from about 6 to about 22 carbon atoms. Further examples of non-ionic surfactants include the condensation products of fatty acids with glucamines, such as C12-C16 akyl N-methyl glucamide, and/or the condensation product of fatty acids with eth-oxylated amines; C10-C20 alkyl mono- or di-alkanolamides, where the alkyloxy group has 1 to 3 carbon atoms, C10-C20 alkyl mono- or di-alknolamide having an intermediate polyoxyalkylene moiety having 2 to 20 alkyleneoxide groups between the alkyl moiety and the alkanolamide moiety; alkyl amidopropyl dimethylamine; fatty acid alkyl esters, such as sorbitol esters with oleic, myristic, stearic, palmitic acid, and the like, also known under the trade name Tween, such as Tween 20, Tween 40, and Tween 60; alkyl polyglycosides including, for example, C8-C10 alkyl polyglycosides, C12-C16 alkyl polyglycosides, C5 Amyl. Further non-ionic surfactants include glycerol-based surfactants, such as fatty acid polyglyceryl esters like octanoic acid hexaglyceryl ester, decanoic acid tetraglyceryl ester, riccinoleic acid hexaglyceryl ester and cocoic acids tetraglyceryl esters and their mixtures. The term “alkyl” as used hereinabove for the non-ionic sugar-based surfactant refers to saturated linear alkyl residues having 3 to 21 carbon atoms, including hexyl, octyl, decanyl, dodecanyl, tetradecanyl, hexa-decanyl, and octadecanyl.

Typical zwitterionic surfactants include but are not limited to derivatives of aliphatic quaternary ammonium, phosphonium, and sulfonium compounds having linear or ramified alkyl, or alkenyl, or hydroxyl alkyl or alkoxy radicals, one of which having from about 8 to about 18 carbon atoms and another of which containing an anionic group selected from carboxyl, sulfonate, sulfate, succinate, phosphate or phosphonate groups. The alkoxy radicals include typically about 1 to about 10 ethylene oxide moieties or about 1 to about 3 glyceryl moieties. The hydroxyl alkyl radicals comprise typically alkylol moieties having 1 to 3 carbon atoms. A particular class of zwitterionic surfactants includes betaines comprising a quaternized cationic ammonium group and an anionic carboxylate group, separated by at least one methylene group, such as coco dimethylcarboxymethyl betaine, lauryl dimethyl carboxymethyl betaine, lauryl dimethyl alphacarboxyethyl betaine, cetyl dimethyl carboxymethyl betaine, oleyl dimethyl gammacarboxypropyl betaine, lauryl and stearyl bis-(2-hydroxyethyl) carboxymethyl betaine, oleyl dimethyl gammacarboxypropyl betaine, and lauryl bis-(2-hydroxypropyl)alphacarboxyethyl betaine. Other betaines include amidoalkyl, sulfoalkyl and alkyl amidosufo beta-ines, wherein the alkyl moiety is typically an ethyl or a propyl moiety, such as cocoamidopropyl betaine, cocodimethylsulfopropyl betaine, lauryl dimethyl sulfoethyl betaine, lauryl bis-(2-hydroxyethyl) sulfopropyl betaine and the like. Another particular class of zwitterionic surfactants includes sultaines, hydroxysultaines and amidopropyl hydroxysultaines.

Typical Zwitterionic and semi-polar surfactants include water-soluble amine oxides, such as C10-C18 alkyl dimethyl amine oxides and C8-C12 alkoxy ethyl dihydroxy ethyl amine oxides, such as NN-dihydroxyethyl-N-stearamine oxide, ethoxylated lauramide and lauryldimethylamine oxide, also known under the name Lauramine oxide (“LO”), and alkyl amphocarboxylic acids, such as disodium cocoamphodiacetate.

Liquid or solid laundry detergent compositions may be provided in the form of single unit doses contained, for example, in water-dissolvable packaging, such as pouches or pods. Because these products are single dose and of relatively small size (typically about 10 to 20 ml volume), they are provided with a relatively low dose of detergent composition, and furthermore, because the packaging enclosing the detergent is water-soluble, or at least disintegrates readily in water, the composition necessarily contains a small volume of highly concentrated surfactant, and therefore represents a very aggressive medium in which to incorporate microcapsules.

In pouches comprising laundry, laundry additive and/or fabric conditioning compositions, the compositions may comprise one or more of the following non-limiting list of ingredients: fabric care benefit agent; detersive enzyme; deposition aid; rheology modifier; builder; bleach; bleaching agent; bleach precursor; bleach booster; bleach catalyst; polyglycerol esters; whitening agent; pearlescent agent; enzyme stabilizing systems; scavenging agents including fixing agents for anionic dyes, complexing agents for anionic surfactants, and mixtures thereof; optical brighteners or fluorescers; polymer including but not limited to soil release polymer and/or soil suspension polymer; dispersants; antifoam agents; non-aqueous solvent; fatty acid; suds suppressors, e.g., silicone suds suppressors (see: U.S. Publication No. 2003/0060390 A1, ¶ 165-77); cationic starches (see: US 2004/0204337 A1 and US 2007/0219111 A1); scum dispersants (see: US 2003/0126282 A1); substantive dyes; hueing dyes (see: US 2014/0162929A1); colorants; opacifier; antioxidant; hydrotropes such as toluenesulfonates, cumenesulfonates and naphthalenesulfonates; color speckles; colored beads, spheres or extrudates; clay softening agents; anti-bacterial agents. Additionally or alternatively, the compositions may comprise surfactants, quaternary ammonium compounds, and/or solvent systems.

The detergent compositions can comprise from about 1 wt % to 80 wt % by weight of a surfactant. Detersive surfactants utilized can be of the anionic, nonionic, zwitterionic or cationic type or can comprise compatible mixtures of these types. More preferably surfactants are selected from the group consisting of anionic, nonionic, cationic surfactants and mixtures thereof. Detergent surfactants useful herein are described in U.S. Pat. Nos. 3,664,961; 3,919,678; 4,222,905; and 4,239,659. Anionic and nonionic surfactants are preferred. Useful anionic, nonionic, zwitterionic or cationic type surfactants are those described above.

Laundry detergent compositions may have a pH of about 6 to about 10, about 6.5 to about 8.5, about 7 to about 7.5, or about 8 to about 10, wherein the pH of the detergent is defined as the pH of an aqueous 10% (weight/volume) solution of the detergent at 20±2° C.

In yet another embodiment of the present invention the consumer product is a personal care product, such as shampoos, hair conditioners and personal cleansing compositions. Examples of shampoos and hair conditioner formulations and ingredients are described in US patents 6,162,423; 5,968,286; 5,935,561; 5,932,203; 5,837,661; 5,776,443; 5,756,436; 5,661,118; and 5,618,523.

Hair cleansing compositions—shampoos—comprise at least one surfactant selected from anionic, non-ionic and/or zwitterionic surfactants, typically at a concentration range of 2 to 60 wt %, more particularly 5 to 50 wt % and more particularly 5 to 40 wt % based on the total weight of the composition.

Any of the anionic, non-ionic and/or zwitterionic surfactants referred to above may be employed in hair cleansing compositions.

Anionic surfactants may be present in an amount from 1 to about 30 wt %, particularly 2 to 25 wt % and most particularly 2-20 wt %.

Non-ionic surfactants may be employed in an amount from about 0.25 wt % to about 5 wt %, particularly about 0.5 wt % to about 3.5 wt % based on the total composition.

Zwitterionic surfactants may be employed in an amount of about 0.5 wt % to about 10 wt %, more particularly from about 1 wt % to about 7.5 wt % by weight based on the total weight of the composition.

Hair conditioning compositions of the present invention can be in the form of either leave in or rinse off compositions.

Preferred surfactants are non-ionic and cationic types and they may be employed in the amounts referred to above in relation to the hair cleaning compositions.

Suitable cationic surfactants and or conditioning agents are, for example, long-chain quaternary ammonium compounds which can be used alone or in admixture with one another, such as cetyl trimethyl ammonium chloride, myristoyl trimethyl ammonium chloride, trimethyl cetyl ammonium bromide, stearyl trimethyl ammonium chloride, dimethyl stearyl ammonium chloride, dimethyl dihydrogenated tallow ammonium chloride, stear trimonium chloride, dipalmitoyl dimonium chloride, distearyl dimethyl ammonium chloride, stearamidopropyl trimonuim chloride, and dioleoylethyl dimethyl ammonium methosulfate.

Particularly useful are so-called esterquats, which are well known commercial ingredients, such as those available under the trade names “Schercoquat™”, “Dehyquart™ F30” and “Tetranyl™ ”. Use of the esterquats in hair care compositions is described, for example, in WO-A 93/107 48, WO-A 92/068 99 and WO-A 94/166 77.

Hair conditioning compositions may contain cationic polymers as conditioning agents. Cationic conditioning agents include but are not limited to cellulose type polymers, such as Polyquaternium 10 or cationic guar gum, such as Guar hydroxypropyl trimonium chloride. Other cationic conditioning agents include natural cationic polymers, such as chitosan and chitin. Other polymers include Polyquaternium 6, Polyquaternium 7, Polyquaternium 10, Polyquaternium 11, Polyquaternium 16, Polyquaternium 22 and Polyquaternium 28, Polyquaternium 30, Polyquaternium 37, Polyquaternium 36, and Polyquaternium 46. Still further, Quaternium-8, Quaternium-14, Quaternium-15, Quaternium-18, Quaternium-22, Quatemium-24, Quaternium-26, Quaternium-27, Quatemium-30, Quatemium-33, Quaternium-53, Quatemium-60, Quaternium-61, Quaternium-72, Quatemium-78, Quaternium-80, Quaternium-81, Quaternium-81, Quaternium-82, Quaternium-83 and Quatemium-84. It is also possible to use mixtures of various cationic polymers.

The cationic polymers may also include the quatemized products of graft polymers from organopolysiloxanes and polyethyl oxazolines, as described, for example in EP-A 524 612 and EP-A 640 643.

Typically, a hair conditioning composition might contain between 0.01 wt % to 7.5 wt %, preferably 0.05 wt % to 5 wt % of said conditioning agents based on the total weight of the composition.

Other conditioning agents might include volatile or non-volatile silicone oils, including dimethicone, dimethiconol, polydimethylsiloxane, such as the DC fluid ranges available from Dow Coming. Also suitable are natural oils, such as olive oil, almond oil, avocado oil, ricinus oil, coconut oil, palm oil, sesame oil, peanut oil, whale oil, sunflower oil, peach kernel oil, wheat germ oil, macadamia nut oil, night primrose oil, jojoba oil, castor oil, or soya oil, lanolin and the derivatives thereof, as well as mineral oils such as paraffin oil and petrolatum.

Non-ionic conditioning agents may be polyols such as glycerin, glycol and derivatives, polyethyleneglycoles known with trade names Carbowax PEG from Union Carbide and Polyox WSR range from Amerchol, polyglycerin, polyethyleneglycol mono or di fatty acid esters.

Typical concentration range for any of the additional non-cationic conditioning agents mentioned above can be 0.01wt % to 15 wt % based on the total weight of the composition. They may additionally contain at least one saturated or unsaturated fatty alcohol. Fatty alcohols include but are not limited to myristyl alcohol, palmityl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol and their mixtures. The concentration of the fatty alcohol may be less than 20 wt % based on the total weight of the composition.

Conditioner compositions are disclosed in US 2015/0157550, which is hereby incorporated by reference.

EXAMPLE 1

Encapsulated Perfume Compositions for use in Fabric Care Conditioners

Microcapsules were prepared according to the method set forth in WO/2008/098387, example 1.3, sample P5.2, using different perfumes having variable RECON_VOLTAE, log₁₀ Kcaps and PROC values. The solid content of the capsule slurries was 40±2 wt %, wherein “solid content” refers to the percentage by weight of perfume-containing microcapsules in the slurry. In each case, an amount of slurry equivalent to 0.2 wt % of microcapsules was added to a fabric care softener composition having the formula described in Table 1.2. The perfume compositions are reported in Tables 1.1.1 through 1.1.4.

TABLE 1.1.1 Perfume composition 1.A Average Average RECON_VOLTAE Average Odour Sum RECON_VOLTAE Distribution C [%] [Bohr³] LogKcaps Value pPROC RECON_VOLTAE > 1750 0.7 1832 −2.5 212968 7.48E+04 1540 < RECON_VOLTAE > 1750 8.7 1717 −1.8 365443 5.10E+06 1200 < RECON_VOLTAE < 1540 63.1 1381 −1.8 685319 7.31E+07 < RECON_VOLTAE 1200 27.5 1174 −0.7 5129911 2.50E+08

Perfume 1.A had 27.5 wt % of encapsulated perfume ingredients having RECON_VOLTAE lower than 1200; 72.5 wt % of ingredients having RECON_VOLTAE higher than 1200; 9.4 wt % of ingredients having RECON_VOLTAE higher than 1540; and 0.7 wt % of ingredients having RECON_VOLTAE higher than 1750. The total pre-rub odour contribution (tPROC) was 3.3×10⁸. In table 1.1.1, all averages are weighted averages. RECON_VOLTAE<1200 means that RECON_VOLTAE can have any value between from 1 to 1199; 1200<RECON_VOLTAE<1540 means that RECON_VOLTAE can have any value between 1200 and 1539. RECON_VOLTAE>1750 means that RECON_VOLTAE can have any value between from 1750 upwards.

TABLE 1.1.2 Perfume composition 1.B Average Average RECON_VOLTAE Average Odour Sum RECON_VOLTAE Distribution C [%] [Bohr³] LogKcaps Value pPROC RECON_VOLTAE > 1540 41.1 1661 −1.9 1384185 5.58E+07 1200 < RECON_VOLTAE < 1540 53.1 1397 −2.0 2555236 2.66E+08 RECON_VOLTAE < 1200 5.8 1139 −1.8 2095237 2.21E+07

Perfume 1.B had 5.8 wt % of ingredients having RECON_VOLTAE lower than 1200; 94.2 weight percent wt % of ingredients having RECON_VOLTAE higher than 1200; 41.1 wt % of ingredients having RECON_VOLTAE higher than 1540; and 0 wt % of ingredients having RECON_VOLTAE higher than 1750. All ingredients had log₁₀ Kcaps higher than −3, except the ALDEHYDE ISO C 11 and PEACH PURE. The total pre-rub odour contribution (tPROC) was 3.3×10⁸. In table 1.1.2, all averages are weighted averages. RECON_VOLTAE<1200 means that RECON_VOLTAE can have any value between from 1 to 1199; 1200<RECON_VOLTAE<1540 means that RECON_VOLTAE can have any value between 1200 and 1539. RECON_VOLTAE>1540 means that RECON_VOLTAE can have any value between from 1750 upwards.

TABLE 1.1.3 Perfume composition 1.C Average Average RECON_VOLTAE Average Odour Sum RECON_VOLTAE Distribution C [%] [Bohr³] LogKcaps Value pPROC FATTY ESTER 10.4 2379 −1.3 0 0.00E+00 RECON_VOLTAE > 1750 11.6 2085 −2.8 7258 6.97E+04 1540 < RECON_VOLTAE < 1750 47.6 1665 −1.9 8152 4.00E+05 1200 < RECON_VOLTAE < 1540 26.4 1346 −2.0 3965938 2.05E+08 RECON_VOLTAE < 1200 4.0 1155 −2.5 166482 4.61E+05

Perfume 1.0 had 4.0 wt % of ingredients having RECON_VOLTAE lower than 1200; 96 wt % of ingredients having RECON_VOLTAE higher than 1200; 69.6 wt % of ingredients having RECON_VOLTAE higher than 1540; and 22.0 wt % of ingredients having RECON_VOLTAE higher than 1750. The total pre-rub odour contribution (tPROC) was 2.1×10⁸. In table 1.1.3, all averages are weighted averages. RECON_VOLTAE<1200 means that RECON_VOLTAE can have any value between from 1 to 1199; 1200 <RECON_VOLTAE<1540 means that RECON_VOLTAE can have any value between 1200 and 1539. RECON_VOLTAE>1750 means that RECON_VOLTAE can have any value between from 1750 upwards.

TABLE 1.1.4 Perfume composition 1.D Average Average RECON_VOLTAE Average Odour Sum RECON_VOLTAE Distribution C [%] [Bohr³] LogKcaps Value pPROC RECON_VOLTAE > 1750 4.1 2003 −2.0 32323 1.10E+05 1540 < RECON_VOLTAE < 1750 60.1 1662 −2.2 844432 7.54E+07 < 1200 RECON_VOLTAE < 1540 35.0 1371 −1.4 1573063 1.08E+08 RECON_VOLTAE < 1200 0.8 1138 −1.9 811379 7.55E+05

Perfume 1.D had 0.8 wt% of ingredients having RECON_VOLTAE lower than 1200; 99.2 wt 15% of ingredients having RECON_VOLTAE higher than 1200; 64.2 wt % of ingredients having RECON_VOLTAE higher than 1540; and 4.1 wt % of ingredients having RECON_VOLTAE higher than 1750. The total pre-rub odour contribution (tPROC) was 1.64×10⁸. In table 1.1.4, all averages are weighted averages. RECON_VOLTAE<1200 means that RECON_VOLTAE can have any value between from 1 to 1199; 1200<RECON_VOLTAE<1540 means that RECON_VOLTAE can have any value between 1200 and 1539. RECON_VOLTAE>1750 means that RECON_VOLTAE can have any value between from 1750 upwards.

TABLE 1.2 Fabric care softener composition Ingredient Chemical nature Percentage Magnesium chloride 1 wt % REWOQUAT WE 18 Di-(tallow-carboxyethyl)- 12 wt % (ex REWO) hydroxyethyl methylammonium methosulfate GENAPOL O 100 Ethoxylated fatty alcohol 2 wt % (ex HOECHST) (C16-18; 10 EO) ANTIFOAM 110A Polydimethylsiloxane emulsion 1 wt % (EU) (ex DOW stabilized with CORNING) hydroxyethyl cellulose MYACIDE BT 30 2-bromo-2-nitropropane-1, 0.03 wt % (ex BOOTS) 3-diol PROXEL GXL Benzisothiazolinone 0.02 wt % (ex ICI) DEIONIZED WATER sq. 100 wt %

The fabric care softener compositions containing the perfume compositions set forth in Tables 1.1.1 through 1.1.4 were put in a cupboard maintained at 37° C. with a thermostat for one month and the amount of free perfume having leached from the capsules was determined using the method described in Example 5, below.

EXAMPLE 2 Encapsulated Perfume Compositions for use in Liquid Detergent Tabs

Aminoplast microcapsules were prepared according to the following method:

-   -   1. Adding and dissolving a polymer stabilizer (Lupasol PA 140,         ex BASF) in water under moderate shear mixing.     -   2. Adjusting the temperature to 35±2° C., the pH to 4.6±2 with         NaOH, then adding an an alkylolated triamine pre-condensate         (Luracoll SD, ex BASF), urea and perfume composition.     -   3. Emulsifying the system under moderate to high shear mixing,         wherein the stirring speed and the geometry of the mixer is         defined as a function of the desired average microcapsule size         range and microcapsule size distribution.     -   4. Increasing the temperature to 88° C.±1° C. over a period of         75 min, then leaving the reaction at 88 C±2° C. during 2 h15.     -   5. Increasing the temperature to 88° C.±1° C. over a period of         75 min, then leaving the reaction at 88 C±2° C. during 35 min.         Adding a second portion of the alkylolated triamine or triamine         pre-condensates and formic acid.     -   6. Adding ethylene urea as formaldehyde scavenger while the         slurry is still hot (88° C.) for 10 min     -   7. Cooling the system to room temperature.     -   8. Adding Carbopol under solution and leave the agitation         constant 1 h, at 129 rpm, then adding NaOH and optionally         adjusting pH within the range from 6 to 6.6 with formic acid

The perfume compositions employed in the process described above are reported in Tables 2.1.A and 2.1.B. The solid content of the capsule slurries was 30 ±2 wt %, whereas the solid content refers to weight of perfume-containing capsules (wt %). In each case, an amount of slurry equivalent to 0.2 wt % of perfume-containing capsules was added to a liquid detergent tab base composition having the formula described in Table 2.2.

TABLE 2.1.1 Perfume composition 2.A Average Average RECON_VOLTAE Average Odour Sum RECON_VOLTAE Distribution C [%] [Bohr³] LogKcaps Value pPROC RECON_VOLTAE > 1750 18.6 1845 −2.3 69384 8.35E+05 1540 < RECON_VOLTAE < 1750 22.3 1666 −2.0 12520902 2.79E+08 1200 < RECON_VOLTAE < 1750 53.7 1386 −2.0 1387064 1.09E+08 RECON_VOLTAE < 1200 5.5 1100 −1.8 69302 4.57E+05

Perfume 2.A had 5.5 wt % of ingredients having RECON_VOLTAE lower than 1200; 94.5 wt % of ingredients having RECON_VOLTAE higher than 1200; 40.9 wt % of ingredients having RECON_VOLTAE higher than 1540; and 18.6 wt % of ingredients having RECON_VOLTAE higher than 1750. The total pre-rub odour contribution (tPROC) was 3.9×10⁸. In table 2.1.1, all averages are weighted averages. RECON_VOLTAE<1200 means that RECON_VOLTAE can have any value between from 1 to 1199; 1200<RECON_VOLTAE<1540 means that RECON_VOLTAE can have any value between 1200 and 1539. RECON_VOLTAE>1750 means that RECON_VOLTAE can have any value between from 1750 upwards.

TABLE 2.1.2 Perfume composition 2.B Average Average RECON_VOLTAE Average Odour Sum RECON_VOLTAE Distribution C [%] [Bohr³] LogKcaps Value pPROC RECON_VOLTAE > 1750 6.6 1966 −1.5 54255 5.42E+05 1540 < RECON_VOLTAE < 1750 59.9 1677 −2.3 50774 2.26E+06 1200 < RECON_VOLTAE < 1540 26.4 1374 −1.7 4034852 1.39E+08 RECON_VOLTAE < 1200 7.1 1155 −1 361183 4.45E+06

Perfume 2.B had 7.1 wt % of ingredients having RECON_VOLTAE lower than 1200; 92.9 wt % of ingredients having RECON_VOLTAE higher than 1200; 66.5 wt % of ingredients having RECON_VOLTAE higher than 1540; and 6.6 wt % of ingredients having RECON_VOLTAE higher than 1750. The total pre-rub odour contribution (tPROC) was 1.5×10⁸. In table 2.1.2, all averages are weighted averages. RECON_VOLTAE<1200 means that RECON_VOLTAE can have any value between from 1 to 1199; 1200<RECON_VOLTAE<1540 means that RECON_VOLTAE can have any value between 1200 and 1539. RECON_VOLTAE>1750 means that RECON_VOLTAE can have any value between from 1750 upwards.

TABLE 2.2 Liquid detergent tab base composition Ingredient Chemical nature Percentage DEIONIZED WATER 10 wt % PROPYLENE 20 wt % GLYCOL (ex MERCK) GLYCEROL Propan-1,2,3 triol 18.5 wt %   (ex Merck) TEXAPON N 70 Sodium Lauryl Ether Sulfate + 16.33 wt %   (ex COGNIS) 2EO BIO SOFT LA ACID Acid benzenesulfonic  5 wt % (ex STEPAN) LASACID FC 12 Lauric acid 99%  5 wt % (ex LASCARAY SA) M.E.A Monoethanolamine 10 wt % (ex BASF) NEODOL 25-7 Ethoxylated Alcohol 15 wt % (ex CALDIC) C12-C15 BRONIDOX L 2-bromo-2-nitropropane 0.03 wt %   (ex COGNIS)

The liquid detergent base containing above perfume compositions were put in a thermostated cupboard at 37° C. for one month and the amount of free perfume having leached from the capsules was determined using the method described in Example 5.

EXAMPLE 3

Perfume Compositions for use in Hair Care Conditioners

Polyurea core-shell capsules were prepared by poly-condensation of polyisocyanates and polyamines, according to the procedure disclosed WO 2011/160733 A1. The perfume compositions are reported in Table 3.1. The solid content of the capsule slurries was 40±2 wt %.

TABLE 3.1 Perfume 3 A composition Average Average RECON_VOLTAE Average Odour Average RECON_VOLTAE Distribution C [%] [Bohr³] LogKcaps Value pPROC RECON_VOLTAE > 1750 4.6 1822 −1.9 11675 5.96E+04 1540 < RECON_VOLTAE < 1750 41.4 1679 −2.0 210856 1.15E+07 1200 < RECON_VOLTAE < 1540 43.2 1415 −2.5 188189 4.91E+06 RECON_VOLTAE < 1200 11.0 1032 −1.9 3559766 4.25E+07

Perfume 3 A had 11.0 wt % of ingredients having RECON_VOLTAE lower than 1200; 89.0 wt % of ingredients having RECON_VOLTAE higher than 1200; 45.8 wt % of ingredients having RECON_VOLTAE higher than 1540; and 4.6 wt % of ingredients having RECON_VOLTAE higher than 1750. The total pre-rub odour contribution (tPROC) was 5.9×10⁷. In table 3.1, all averages are weighted averages. RECON_VOLTAE<1200 means that RECON_VOLTAE can have any value between from 1 to 1199; 1200<RECON_VOLTAE<1540 means that RECON_VOLTAE can have any value between 1200 and 1539. RECON_VOLTAE>1750 means that RECON_VOLTAE can have any value between from 1750 upwards.

TABLE 4.2 Hair conditioner composition Ingredient Chemical nature Percentage PHENONIP Phenoxyethanol and Butyl 0.7 wt % (ex CLARIANT) and Ethyl and Propyl parabens LANETTE 16 Cetyl alcohol 1.0 wt % (ex COGNIS) BRIJ 721 Steareth 21 2.0 wt % (ex UNIQEMA/MASSO) STEARAFINE PURE Stearyl alcohol 1.0 wt % (ex LASERSON) PROPYLENE GLYCOL 4.0 wt % (ex PRODH'YG) NATROSOL 250H Hydroxyethyl cellulose 0.9 wt % (ex AQUALON) INCROQUAT CTC 30 Cetrimonium chloride 2.00 wt % (ex CRODA) DEIONISED WATER q.s.p. 100 wt %

The hair conditioner base containing above perfume compositions were put in a thermostated cupboard at 37° C. for one month and the amount of free perfume having leached from the capsules was determined using the method described in Example 5.

EXAMPLE 4

Perfume Compositions for use in Shampoo

Polyurea core-shell capsules were prepared by poly-condensation of polyisocyanates and polyamines, according to the procedure disclosed WO 2011/160733 A1. The perfume composition is reported in Table 4.1. The solid content of the capsule slurries was 40±2 wt %.

TABLE 4.1 Perfume composition 4 A Average Average RECON_VOLTAE Average Odour Sum RECON_VOLTAE Distribution C [%] [Bohr³] LogKcaps Value pPROC RECON_VOLTAE > 1750 89.1 2226 −1.8 9253 1.23E+06 1450 < RECON < 1750 5.9 1573 −2.2 355731 1.68E+06 1200 < RECON VOLTAE < 1540 4 1417.698 −1.747203 207333 1.04E+06 RECON VOLTAE < 1200 1 885.487 −2.7870302 10337115 1.95E+07

Perfume 4 A had 1 wt % of ingredients having RECON_VOLTAE lower than 1200; 95% of ingredients having RECON_VOLTAE higher than 1540 and 89.1 wt % of ingredients having RECON_VOLTAE higher than 1750. The total pre-rub odour contribution (tPROC) was 2.3×10⁷. In table 4.1, all averages are weighted averages. RECON_VOLTAE<1750 means that RECON_VOLTAE can be any value between from 1 to 1749. RECON_VOLTAE>1750 means that RECON_VOLTAE can be any value between from 1750 upwards.

TABLE 4.2 Shampoo base composition Ingredient Chemical nature Percentage DEIONIZED WATER 67.00 wt %  PROPYLENE GLYCOL 0.67 wt % (ex MERCK) JR-125 (ex RHODIA) Polyquaternium-10 0.17 wt % GENAPOL LRO LIQ Sodium Laureth Sulfate 20.09 wt %  (ex CLARIANT) DEHYTON AB 30 Coco Betaine 4.02 wt % (ex COGNIS) GLYDANT PLUS LIQ DMDM Hydantoin 0.33 wt % (ex LONZA) TRILON B Tetrasodium EDTA 0.03 wt % (ex BASF) SODIUM CHLORIDE 1.00 wt % (ex MERCK)

The shampoo base containing above perfume compositions were put in a thermostated cupboard at 37° C. for one month and the amount of free perfume having leached from the capsules was determined using the method described in Example 5.

EXAMPLE 5

Determination of Capsule Leakage in Consumer Product Bases

1 g of consumer product base sample, previously filtered through a 5 micrometre syringe filter was accurately weighed in a 30 ml flask. 1 g of Celite 545 was added and admixed with the sample. 10 ml of pentane was then added together with 0.5 mg of internal standard (Methyl decanoate 99% Aldrich ref 299030) to the sample. The whole was stirred for 30 minutes using a magnetic stirrer. The pentane phase was then removed and an aliquot of 2 microlitre was injected in a gas chromatograph (GC) equipped with a splitless injector and a flame ionization detector. The initial temperature of the GC oven was 70° C., the final temperature, 240° C. and the rate of hating was set to 2° C./min. The temperature of the injector was 250° C. A RTX1 GC column with dimensions 60 m*0.25 μm*0.25 μm was used.

Table 3.1 summarizes the results from capsule leakage analysis, along with RECON_VOLTAE and PROC values.

TABLE 3.1 Perfume Ingredients Composition/ Ingredients with 1200 < Ingredients Ingredients LEAKAGE 1 Application with RV > RV < 1540 with RV > with RV > Total month 37° C. Capsules 1200 (wt %) (wt %) 1540 (wt %) 1750 (wt %) PROC (wt %) 1.A/Fabric 72.5 63.1 9.4 0.7 3.4 × 10⁸ 72.6 care softener Aminoplast 1.B/Fabirc 94.2 53.1 41.1 0.0 3.5 × 10⁸ 47.0 care softener; Aminoplast 1.C/Fabric 96.0 26.4 69.6 22.0 2.1 × 10⁸ 20.2 care softener; Aminoplast 1.D/Fabric 99.2 35 64.2 4.1 1.7 × 10⁸ 14.6 care softener; Aminoplast 2 A/liquid 94.5 53.7 40.9 18.6 3.9 × 10⁸ 50 detergent tabs Aminoplast 2 B/liquid 92.9 26.4 66.5 6.6 1.5 × 10⁸ 15 detergent tabs Aminoplast 3 A/Shampoo 89.0 43.2 45.8 4.6 5.9 × 10⁷ 60 PU(*) 4 A/Shampoo 99 4 95 89.1 2.3 × 10⁷ <10 PU(*) (*)The Capsules PU were obtained as described in WO 2011/0058929 A1, example 2.

The results show a clear correlation between the RECON_VOLTAE value distribution and the leakage. Furthermore, the results show also that it is possible to obtain perfume compositions that not only are stable under various storage conditions, while still being diffusive, as illustrated by the high tPROC values. Conversely, it is possible to obtain very stable perfume compositions, using high level of high RECON_VOLTAE materials, but then the pre-rub impact may then decrease below an acceptable value (see for example, the case of perfume 4 A in shampoos).

EXAMPLE 6

A series of perfumes were encapsulated by using the process described in Example 2. In these cases, both the distribution of RECON_VOLTAE values and the total Pre-Rub Odour Contribution (tPROC) was varied. The capsule were dispersed in the liquid detergent base for liquid tabs described in Example 2. Wash tests were performed after one month storage in thermostated hood at 37° C., using standard front-loaded wash machine and terry towelling as standard substrate. The pre-rub performance was evaluated by smelling the towel on dry towel, taking care not to break the capsules. A panel of 10 trained panellists was used. Both evaluation scores and characteristics of the encapsulated perfumes are reported in Table 6. The following relative scale was used: 1: barely noticeable odour, 2: medium odour strength, 3: strong odour and 4: very strong odour.

TABLE 6 Perfume features and capsule pre-rub performance in liquid detergent tabs after storage (RV means RECON_VOLTAE and the total Pre Rub Odour Contribution (tPROC) has been divided by 10⁸ for clarity) RV >1200 RV >1540 RV >1750 tPROC/10⁸ SCORE 90.95 31.00 8.50 3.3 4 93.50 75.30 2.50 2.5 4 90.00 33.00 2.00 6.7 4 96.90 84.30 2.50 3.6 4 93.00 66.80 8.00 2.1 3 100.00 50.00 2.00 1.1 3 97.00 53.00 0.00 2 3 97.00 55.50 9.00 2.7 3 100.00 42.50 7.00 1.1 3 97.00 35.00 14.00 4.4 3 100.00 55.40 15.00 0.6 3 91.65 39.45 18.00 2 3 92.85 52.60 25.50 1 3 96.00 51.50 51.50 1.6 1 93.00 55.78 28.49 1.4 1 100.00 85.00 35.00 0.2 1

As apparent from the results in Table 6, there is a clear optimum in terms of both RECON_VOLTAE distribution and tPROC distribution. The relevance of the pPROC parameter is also demonstrated. As mentioned in Example 5, high levels of ingredients having RECON_VOLTAE values higher than 1750 are beneficial to capsule resistance against leakage during storage, but is deleterious to pre-rub impact. The present example teaches that it is advantageous not to use RV>1750 ingredients at levels higher than 20 to 25 wt % in the encapsulated perfume composition of the present invention. 

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 21. A method of selecting perfume ingredients for an encapsulated perfume composition, comprising the steps of (i) determining the RECON-VOLTAE values of the perfume ingredients, wherein the RECON_VOLTAE value is the integral of the molecular iso-surface having an electron density equal to 0.002 e /a₀ ³ wherein e is the dimension-less electron charge and a₀ is the Bohr radius of the hydrogen atom; and (ii) selecting the ingredients such that more than 70 wt % of the perfume ingredients have known RECON_VOLTAE values larger than about 1200 Bohr³.
 22. The method of claim 21, wherein more than 80 wt %, and more particularly more than 90 wt % of the perfume ingredients have known RECON_VOLTAE values larger than about 1200 Bohr³.
 23. The method of claim 21, wherein more than 30 wt %, more particularly more than 35 wt %, and more particularly still, more than 40 wt % of the perfume ingredients have known RECON_VOLTAE values larger than about 1540 Bohr³.
 24. The method according claim 1, wherein more than 70 wt %, more particularly, more than 80 wt%, and more particularly still, more than 90 wt % of perfume ingredients have known RECON_VOLTAE values larger than about 1750 Bohr³.
 25. The method according to claim 1, wherein at least 3 perfume ingredients, more particularly at least 5, still more particularly at least 7 and more particularly still at least 9 perfume ingredients having RECON_VOLTAE values larger than about 1200 Bohr³.
 26. The method according claim 1, wherein 30 wt % or more, more particularly 35 wt % or more, and more particularly 40 wt % or more of perfume ingredients have known RECON_VOLTAE values larger than 1540 Bohr³; 20 to 60 wt %, more particularly 25 to 50 wt % and more particularly still 30 to 40 wt % of the perfume ingredients have known RECON_VOLTAE values from 1200 Bohr³ to 1540 Bohr³; and 0.1 to 30 wt %, more particularly from 1 to 20 wt % and more particularly still, from 1 to 10 wt% of the perfume ingredients have known RECON_VOLTAE values below 1200 Bohr³.
 27. The method according to claim 1, wherein from 0.5 to 30 wt %, more particularly from 1 to 25 wt %, and more particularly still from 5 to 20 wt % of the perfume ingredients have known RECON_VOLTAE values above 1750 Bohr³; 20 to 60 wt %, more particularly 25 to 55 wt % or more, more particularly still from 30 to 50 wt % or more of the perfume ingredients having known RECON_VOLTAE values from 1540 Bohr³ to 1750 Bohr³; and 5 to 50 wt % or more, more particularly 10 to 40 wt % or more particularly still 15 to 30 wt % or more of the perfume ingredients have known RECON_VOLTAE values from 1200 Bohr³ to 1540 Bohr³; and 0.1 to 30 wt %, more particularly from 1 to 20 wt % and more particularly still from 1 to 10 wt % of perfume ingredients have known RECON_VOLTAE values below 1200 Bohr³.
 28. The method according claim 1, wherein the perfume ingredients have a log₁₀ Kcaps value greater than −3.
 29. The method according to claim 1, wherein the total Pre-Rub Odour Contribution of the perfume ingredients is between about 0.5×10⁸ and 1.0×10⁹, more particularly between 1×10⁸ and 8×10⁸ and more particularly still between 1.5×10⁸ and 6×10⁸.
 30. A method of preparing an encapsulated perfume composition comprising at least one core-shell microcapsule dispersed in a suspending medium, the method comprising the steps of (a) selecting perfume ingredients according to the method of claim 1, and (b) mixing together said perfume ingredients.
 31. The method according to claim 30, wherein the core to shell weight ratio of the microcapsules is about 90:10 at least, or more particularly 95:5 at least, said method comprising the step of encapsulating the perfume composition.
 32. A method of forming a consumer product comprising the step of incorporating into said consumer product an encapsulated perfume composition made according to the method of claim
 30. 